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[μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate

In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordin­ated by four O atoms from the deprotonated Schiff base and...

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Detalles Bibliográficos
Autores principales: Fei, Liu, Fang, Zhang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960331/
https://www.ncbi.nlm.nih.gov/pubmed/21201353
http://dx.doi.org/10.1107/S1600536808002080
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author Fei, Liu
Fang, Zhang
author_facet Fei, Liu
Fang, Zhang
author_sort Fei, Liu
collection PubMed
description In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordin­ated by four O atoms from the deprotonated Schiff base and six O atoms from three bidentate nitrate anions. The compound is isostructural with the previously reported Gd(III) analogue [Elmali & Elerman (2004 ▶). Z. Naturforsch. Teil B, 59, 535–540], which was described in the space group P1 with two formula units in the asymmetric unit. The crystal stucture is, in fact, centrosymmetric and is described here in the space group P [Image: see text] with one formula unit in the asymmetric unit.
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spelling pubmed-29603312010-12-30 [μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate Fei, Liu Fang, Zhang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordin­ated by four O atoms from the deprotonated Schiff base and six O atoms from three bidentate nitrate anions. The compound is isostructural with the previously reported Gd(III) analogue [Elmali & Elerman (2004 ▶). Z. Naturforsch. Teil B, 59, 535–540], which was described in the space group P1 with two formula units in the asymmetric unit. The crystal stucture is, in fact, centrosymmetric and is described here in the space group P [Image: see text] with one formula unit in the asymmetric unit. International Union of Crystallography 2008-01-25 /pmc/articles/PMC2960331/ /pubmed/21201353 http://dx.doi.org/10.1107/S1600536808002080 Text en © Fei and Fang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fei, Liu
Fang, Zhang
[μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate
title [μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate
title_full [μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate
title_fullStr [μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate
title_full_unstemmed [μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate
title_short [μ-N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate
title_sort [μ-n,n′-bis(3-meth­oxy-2-oxidobenzyl­idene)propane-1,3-diamine]trinitratocopper(ii)terbium(iii) acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960331/
https://www.ncbi.nlm.nih.gov/pubmed/21201353
http://dx.doi.org/10.1107/S1600536808002080
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