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[μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate
In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordinated by four O atoms from the deprotonated Schiff base and...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960331/ https://www.ncbi.nlm.nih.gov/pubmed/21201353 http://dx.doi.org/10.1107/S1600536808002080 |
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author | Fei, Liu Fang, Zhang |
author_facet | Fei, Liu Fang, Zhang |
author_sort | Fei, Liu |
collection | PubMed |
description | In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordinated by four O atoms from the deprotonated Schiff base and six O atoms from three bidentate nitrate anions. The compound is isostructural with the previously reported Gd(III) analogue [Elmali & Elerman (2004 ▶). Z. Naturforsch. Teil B, 59, 535–540], which was described in the space group P1 with two formula units in the asymmetric unit. The crystal stucture is, in fact, centrosymmetric and is described here in the space group P [Image: see text] with one formula unit in the asymmetric unit. |
format | Text |
id | pubmed-2960331 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29603312010-12-30 [μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate Fei, Liu Fang, Zhang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordinated by four O atoms from the deprotonated Schiff base and six O atoms from three bidentate nitrate anions. The compound is isostructural with the previously reported Gd(III) analogue [Elmali & Elerman (2004 ▶). Z. Naturforsch. Teil B, 59, 535–540], which was described in the space group P1 with two formula units in the asymmetric unit. The crystal stucture is, in fact, centrosymmetric and is described here in the space group P [Image: see text] with one formula unit in the asymmetric unit. International Union of Crystallography 2008-01-25 /pmc/articles/PMC2960331/ /pubmed/21201353 http://dx.doi.org/10.1107/S1600536808002080 Text en © Fei and Fang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fei, Liu Fang, Zhang [μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate |
title | [μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate |
title_full | [μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate |
title_fullStr | [μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate |
title_full_unstemmed | [μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate |
title_short | [μ-N,N′-Bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate |
title_sort | [μ-n,n′-bis(3-methoxy-2-oxidobenzylidene)propane-1,3-diamine]trinitratocopper(ii)terbium(iii) acetone solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960331/ https://www.ncbi.nlm.nih.gov/pubmed/21201353 http://dx.doi.org/10.1107/S1600536808002080 |
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