3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl

The title compound, C(22)H(28)Br(2)O(2), crystallizes in a staggered arrangement to minimize the inter­actions of its ortho substituents, with a dihedral angle of 84.2 (3)° between the two aromatic rings. Short C—H⋯O hydrogen-bonding inter­actions between meth­oxy groups result in a one-dimensional...

Descripción completa

Detalles Bibliográficos
Autores principales: Polson, Matthew I. J., Steel, Peter J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960332/
https://www.ncbi.nlm.nih.gov/pubmed/21201551
http://dx.doi.org/10.1107/S1600536808002420
_version_ 1782188713973907456
author Polson, Matthew I. J.
Steel, Peter J.
author_facet Polson, Matthew I. J.
Steel, Peter J.
author_sort Polson, Matthew I. J.
collection PubMed
description The title compound, C(22)H(28)Br(2)O(2), crystallizes in a staggered arrangement to minimize the inter­actions of its ortho substituents, with a dihedral angle of 84.2 (3)° between the two aromatic rings. Short C—H⋯O hydrogen-bonding inter­actions between meth­oxy groups result in a one-dimensional polymeric chain of mol­ecules lying parallel to the b axis. One tert-butyl group is disordered equally over two positions.
format Text
id pubmed-2960332
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29603322010-12-30 3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl Polson, Matthew I. J. Steel, Peter J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(28)Br(2)O(2), crystallizes in a staggered arrangement to minimize the inter­actions of its ortho substituents, with a dihedral angle of 84.2 (3)° between the two aromatic rings. Short C—H⋯O hydrogen-bonding inter­actions between meth­oxy groups result in a one-dimensional polymeric chain of mol­ecules lying parallel to the b axis. One tert-butyl group is disordered equally over two positions. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960332/ /pubmed/21201551 http://dx.doi.org/10.1107/S1600536808002420 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Polson, Matthew I. J.
Steel, Peter J.
3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl
title 3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl
title_full 3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl
title_fullStr 3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl
title_full_unstemmed 3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl
title_short 3,3′-Dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl
title_sort 3,3′-dibromo-5,5′-di-tert-butyl-2,2′-dimethoxy­biphen­yl
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960332/
https://www.ncbi.nlm.nih.gov/pubmed/21201551
http://dx.doi.org/10.1107/S1600536808002420
work_keys_str_mv AT polsonmatthewij 33dibromo55ditertbutyl22dimethoxybiphenyl
AT steelpeterj 33dibromo55ditertbutyl22dimethoxybiphenyl

Ejemplares similares