catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)]

The title compound, [ZnCl(2)(C(12)H(8)N(4)S)](n), was obtained by crystallization of 2,5-di-4-pyridyl-1,3,4-thia­diazole with ZnCl(2) in an MeOH/CHCl(3) solvent system. The structure contains infinite chains of ZnCl(2) units connected by the bifunctional thia­diazole ligands, with Zn(II) adopting a...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Li-Juan, Yang, Ming-Xing, Chen, Xiao-Hua, Lin, Shen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960333/
https://www.ncbi.nlm.nih.gov/pubmed/21201344
http://dx.doi.org/10.1107/S1600536808001967
_version_ 1782188714214031360
author Chen, Li-Juan
Yang, Ming-Xing
Chen, Xiao-Hua
Lin, Shen
author_facet Chen, Li-Juan
Yang, Ming-Xing
Chen, Xiao-Hua
Lin, Shen
author_sort Chen, Li-Juan
collection PubMed
description The title compound, [ZnCl(2)(C(12)H(8)N(4)S)](n), was obtained by crystallization of 2,5-di-4-pyridyl-1,3,4-thia­diazole with ZnCl(2) in an MeOH/CHCl(3) solvent system. The structure contains infinite chains of ZnCl(2) units connected by the bifunctional thia­diazole ligands, with Zn(II) adopting a distorted tetra­hedral coordination geometry. The dihedral angle between the two pyridyl rings in each ligand is 34.3 (1)°, and the dihedral angles between the thia­diazole ring and the two pyridyl rings are 18.3 (2) and 16.1 (2)°. The shortest Zn⋯Zn distance within each polymeric chain is 11.862 (3) Å, while the shortest inter­chain Zn⋯Zn distance is 7.057 (3) Å.
format Text
id pubmed-2960333
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29603332010-12-30 catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)] Chen, Li-Juan Yang, Ming-Xing Chen, Xiao-Hua Lin, Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ZnCl(2)(C(12)H(8)N(4)S)](n), was obtained by crystallization of 2,5-di-4-pyridyl-1,3,4-thia­diazole with ZnCl(2) in an MeOH/CHCl(3) solvent system. The structure contains infinite chains of ZnCl(2) units connected by the bifunctional thia­diazole ligands, with Zn(II) adopting a distorted tetra­hedral coordination geometry. The dihedral angle between the two pyridyl rings in each ligand is 34.3 (1)°, and the dihedral angles between the thia­diazole ring and the two pyridyl rings are 18.3 (2) and 16.1 (2)°. The shortest Zn⋯Zn distance within each polymeric chain is 11.862 (3) Å, while the shortest inter­chain Zn⋯Zn distance is 7.057 (3) Å. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960333/ /pubmed/21201344 http://dx.doi.org/10.1107/S1600536808001967 Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Li-Juan
Yang, Ming-Xing
Chen, Xiao-Hua
Lin, Shen
catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)]
title catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)]
title_full catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)]
title_fullStr catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)]
title_full_unstemmed catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)]
title_short catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) N (2):N (5)]
title_sort catena-poly[[dichloridozinc(ii)]-μ-2,5-di-4-pyridyl-1,3,4-thia­diazole-κ(2) n (2):n (5)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960333/
https://www.ncbi.nlm.nih.gov/pubmed/21201344
http://dx.doi.org/10.1107/S1600536808001967
work_keys_str_mv AT chenlijuan catenapolydichloridozinciim25di4pyridyl134thiadiazolek2n2n5
AT yangmingxing catenapolydichloridozinciim25di4pyridyl134thiadiazolek2n2n5
AT chenxiaohua catenapolydichloridozinciim25di4pyridyl134thiadiazolek2n2n5
AT linshen catenapolydichloridozinciim25di4pyridyl134thiadiazolek2n2n5

Ejemplares similares