trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)

The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy­thio­phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution....

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Detalles Bibliográficos
Autores principales: Cao, Ruixia, Wang, Qibao, Sun, Hongjian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960343/
https://www.ncbi.nlm.nih.gov/pubmed/21201261
http://dx.doi.org/10.1107/S1600536807067591
Descripción
Sumario:The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy­thio­phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio­phenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.

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