trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)

The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy­thio­phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution....

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Detalles Bibliográficos
Autores principales: Cao, Ruixia, Wang, Qibao, Sun, Hongjian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960343/
https://www.ncbi.nlm.nih.gov/pubmed/21201261
http://dx.doi.org/10.1107/S1600536807067591
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author Cao, Ruixia
Wang, Qibao
Sun, Hongjian
author_facet Cao, Ruixia
Wang, Qibao
Sun, Hongjian
author_sort Cao, Ruixia
collection PubMed
description The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy­thio­phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio­phenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.
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spelling pubmed-29603432010-12-30 trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II) Cao, Ruixia Wang, Qibao Sun, Hongjian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy­thio­phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio­phenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960343/ /pubmed/21201261 http://dx.doi.org/10.1107/S1600536807067591 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Cao, Ruixia
Wang, Qibao
Sun, Hongjian
trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)
title trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)
title_full trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)
title_fullStr trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)
title_full_unstemmed trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)
title_short trans-Bis(4-methoxy­thio­phenolato-κS)bis­(trimethyl­phosphine-κP)nickel(II)
title_sort trans-bis(4-methoxy­thio­phenolato-κs)bis­(trimethyl­phosphine-κp)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960343/
https://www.ncbi.nlm.nih.gov/pubmed/21201261
http://dx.doi.org/10.1107/S1600536807067591
work_keys_str_mv AT caoruixia transbis4methoxythiophenolatoksbistrimethylphosphinekpnickelii
AT wangqibao transbis4methoxythiophenolatoksbistrimethylphosphinekpnickelii
AT sunhongjian transbis4methoxythiophenolatoksbistrimethylphosphinekpnickelii

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