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Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II)

The molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring in a boat conformation in which the Zn atom is coordinated by two Br atoms and by the two pyridyl N atoms of a single di-2-pyridyl sulfide (dps) ligand within a slightly distorted tetra­hedron. The di...

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Detalles Bibliográficos
Autores principales: Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960344/
https://www.ncbi.nlm.nih.gov/pubmed/21201286
http://dx.doi.org/10.1107/S1600536808000081
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author Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wriedt, Mario
collection PubMed
description The molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring in a boat conformation in which the Zn atom is coordinated by two Br atoms and by the two pyridyl N atoms of a single di-2-pyridyl sulfide (dps) ligand within a slightly distorted tetra­hedron. The dihedral angle between the pyridine rings is 52.7 (1)°. As is usual for this type of complex, the sulfide group does not participate in the zinc coordination.
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spelling pubmed-29603442010-12-30 Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II) Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring in a boat conformation in which the Zn atom is coordinated by two Br atoms and by the two pyridyl N atoms of a single di-2-pyridyl sulfide (dps) ligand within a slightly distorted tetra­hedron. The dihedral angle between the pyridine rings is 52.7 (1)°. As is usual for this type of complex, the sulfide group does not participate in the zinc coordination. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960344/ /pubmed/21201286 http://dx.doi.org/10.1107/S1600536808000081 Text en © Wriedt et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wriedt, Mario
Jess, Inke
Näther, Christian
Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II)
title Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II)
title_full Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II)
title_fullStr Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II)
title_full_unstemmed Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II)
title_short Dibromido(di-2-pyridyl sulfide-κ(2) N,N′)zinc(II)
title_sort dibromido(di-2-pyridyl sulfide-κ(2) n,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960344/
https://www.ncbi.nlm.nih.gov/pubmed/21201286
http://dx.doi.org/10.1107/S1600536808000081
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