Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II)

In the title compound, (C(5)H(5)ClN)(2)[NiCl(4)], the dianion lies on a twofold rotation axis. Two cations are linked to each anion by classical N—H⋯Cl hydrogen bonds, and short Cl⋯Cl contacts and Cl⋯π stacking inter­actions [with distances of 3.376 (2) and 3.684 (2) Å, respectively] extend this pat...

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Detalles Bibliográficos
Autores principales: Cao, Lili, Englert, Ulli, Li, Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960349/
https://www.ncbi.nlm.nih.gov/pubmed/21201332
http://dx.doi.org/10.1107/S1600536808001360
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author Cao, Lili
Englert, Ulli
Li, Qi
author_facet Cao, Lili
Englert, Ulli
Li, Qi
author_sort Cao, Lili
collection PubMed
description In the title compound, (C(5)H(5)ClN)(2)[NiCl(4)], the dianion lies on a twofold rotation axis. Two cations are linked to each anion by classical N—H⋯Cl hydrogen bonds, and short Cl⋯Cl contacts and Cl⋯π stacking inter­actions [with distances of 3.376 (2) and 3.684 (2) Å, respectively] extend this pattern into a chain. The [NiCl(4)](2−) anion shows significant deviation from ideal tetra­hedral geometry.
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spelling pubmed-29603492010-12-30 Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II) Cao, Lili Englert, Ulli Li, Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(5)ClN)(2)[NiCl(4)], the dianion lies on a twofold rotation axis. Two cations are linked to each anion by classical N—H⋯Cl hydrogen bonds, and short Cl⋯Cl contacts and Cl⋯π stacking inter­actions [with distances of 3.376 (2) and 3.684 (2) Å, respectively] extend this pattern into a chain. The [NiCl(4)](2−) anion shows significant deviation from ideal tetra­hedral geometry. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960349/ /pubmed/21201332 http://dx.doi.org/10.1107/S1600536808001360 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Cao, Lili
Englert, Ulli
Li, Qi
Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II)
title Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II)
title_full Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II)
title_fullStr Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II)
title_full_unstemmed Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II)
title_short Bis(4-chloro­pyridinium) tetra­chlorido­nickelate(II)
title_sort bis(4-chloro­pyridinium) tetra­chlorido­nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960349/
https://www.ncbi.nlm.nih.gov/pubmed/21201332
http://dx.doi.org/10.1107/S1600536808001360
work_keys_str_mv AT caolili bis4chloropyridiniumtetrachloridonickelateii
AT englertulli bis4chloropyridiniumtetrachloridonickelateii
AT liqi bis4chloropyridiniumtetrachloridonickelateii

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