Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II)

The title compound, [Ni(C(3)H(10)N(2))(3)][Ni(CN)(4)], is built up of [Ni(pn)(3)](2+) cations (pn is 1,2-diamino­propane) and [Ni(CN)(4)](2−) anions. Both Ni(II) atoms in the cation and the anion lie on a mirror plane. The respective ions inter­act through Coulombic forces and through a complex netw...

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Detalles Bibliográficos
Autores principales: Kuchár, Juraj, Černák, Juraj
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960350/
https://www.ncbi.nlm.nih.gov/pubmed/21201293
http://dx.doi.org/10.1107/S1600536807068420
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author Kuchár, Juraj
Černák, Juraj
author_facet Kuchár, Juraj
Černák, Juraj
author_sort Kuchár, Juraj
collection PubMed
description The title compound, [Ni(C(3)H(10)N(2))(3)][Ni(CN)(4)], is built up of [Ni(pn)(3)](2+) cations (pn is 1,2-diamino­propane) and [Ni(CN)(4)](2−) anions. Both Ni(II) atoms in the cation and the anion lie on a mirror plane. The respective ions inter­act through Coulombic forces and through a complex network of hydrogen bonds. Extended disorder associated with the cation has been resolved. The occupancies of the respective disordered positions are 0.4:0.4:0.2.
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spelling pubmed-29603502010-12-30 Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II) Kuchár, Juraj Černák, Juraj Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(3)H(10)N(2))(3)][Ni(CN)(4)], is built up of [Ni(pn)(3)](2+) cations (pn is 1,2-diamino­propane) and [Ni(CN)(4)](2−) anions. Both Ni(II) atoms in the cation and the anion lie on a mirror plane. The respective ions inter­act through Coulombic forces and through a complex network of hydrogen bonds. Extended disorder associated with the cation has been resolved. The occupancies of the respective disordered positions are 0.4:0.4:0.2. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960350/ /pubmed/21201293 http://dx.doi.org/10.1107/S1600536807068420 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Kuchár, Juraj
Černák, Juraj
Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II)
title Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II)
title_full Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II)
title_fullStr Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II)
title_full_unstemmed Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II)
title_short Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidonickelate(II)
title_sort tris(propane-1,2-diamine-κ(2) n,n′)nickel(ii) tetra­cyanidonickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960350/
https://www.ncbi.nlm.nih.gov/pubmed/21201293
http://dx.doi.org/10.1107/S1600536807068420
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AT cernakjuraj trispropane12diaminek2nnnickeliitetracyanidonickelateii

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