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[(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol
The title compound, C(35)H(38)N(4)O(3), was prepared as a spirolactam ring formation of rhodamine dye for comparison with a ring-opened form. The xanthene ring system is approximately planar. The dihedral angles formed by the spirolactam and phenol rings with the xanthene ring system are 85.7 and...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960358/ https://www.ncbi.nlm.nih.gov/pubmed/21201431 http://dx.doi.org/10.1107/S1600536807068742 |
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author | Zhang, Li-Zhu Peng, Xiao-Jun Gao, Shang Fan, Jiang-Li |
author_facet | Zhang, Li-Zhu Peng, Xiao-Jun Gao, Shang Fan, Jiang-Li |
author_sort | Zhang, Li-Zhu |
collection | PubMed |
description | The title compound, C(35)H(38)N(4)O(3), was prepared as a spirolactam ring formation of rhodamine dye for comparison with a ring-opened form. The xanthene ring system is approximately planar. The dihedral angles formed by the spirolactam and phenol rings with the xanthene ring system are 85.7 and 109.4°, respectively. Each of the molecules in the crystal structure contains one intramolecular O—H⋯N hydrogen bond, and they form intermolecular N—H⋯O hydrogen-bonded chains along the [100] direction. Weak intermolecular C—H⋯O hydrogen-bonding contacts connect the infinite chains via crystallographic inversion centres to form a two-dimensional network. |
format | Text |
id | pubmed-2960358 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29603582010-12-30 [(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol Zhang, Li-Zhu Peng, Xiao-Jun Gao, Shang Fan, Jiang-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(35)H(38)N(4)O(3), was prepared as a spirolactam ring formation of rhodamine dye for comparison with a ring-opened form. The xanthene ring system is approximately planar. The dihedral angles formed by the spirolactam and phenol rings with the xanthene ring system are 85.7 and 109.4°, respectively. Each of the molecules in the crystal structure contains one intramolecular O—H⋯N hydrogen bond, and they form intermolecular N—H⋯O hydrogen-bonded chains along the [100] direction. Weak intermolecular C—H⋯O hydrogen-bonding contacts connect the infinite chains via crystallographic inversion centres to form a two-dimensional network. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960358/ /pubmed/21201431 http://dx.doi.org/10.1107/S1600536807068742 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Zhang, Li-Zhu Peng, Xiao-Jun Gao, Shang Fan, Jiang-Li [(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol |
title | [(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol |
title_full | [(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol |
title_fullStr | [(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol |
title_full_unstemmed | [(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol |
title_short | [(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol |
title_sort | [(2-{[3′,6′-bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1h-isoindole-1,9′-9h-xanthen]-2-yl}ethyl)aminomethyl]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960358/ https://www.ncbi.nlm.nih.gov/pubmed/21201431 http://dx.doi.org/10.1107/S1600536807068742 |
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