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[(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol

The title compound, C(35)H(38)N(4)O(3), was prepared as a spiro­lactam ring formation of rhodamine dye for comparison with a ring-opened form. The xanthene ring system is approximately planar. The dihedral angles formed by the spiro­lactam and phenol rings with the xanthene ring system are 85.7 and...

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Detalles Bibliográficos
Autores principales: Zhang, Li-Zhu, Peng, Xiao-Jun, Gao, Shang, Fan, Jiang-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960358/
https://www.ncbi.nlm.nih.gov/pubmed/21201431
http://dx.doi.org/10.1107/S1600536807068742
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author Zhang, Li-Zhu
Peng, Xiao-Jun
Gao, Shang
Fan, Jiang-Li
author_facet Zhang, Li-Zhu
Peng, Xiao-Jun
Gao, Shang
Fan, Jiang-Li
author_sort Zhang, Li-Zhu
collection PubMed
description The title compound, C(35)H(38)N(4)O(3), was prepared as a spiro­lactam ring formation of rhodamine dye for comparison with a ring-opened form. The xanthene ring system is approximately planar. The dihedral angles formed by the spiro­lactam and phenol rings with the xanthene ring system are 85.7 and 109.4°, respectively. Each of the mol­ecules in the crystal structure contains one intra­molecular O—H⋯N hydrogen bond, and they form inter­molecular N—H⋯O hydrogen-bonded chains along the [100] direction. Weak inter­molecular C—H⋯O hydrogen-bonding contacts connect the infinite chains via crystallographic inversion centres to form a two-dimensional network.
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spelling pubmed-29603582010-12-30 [(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol Zhang, Li-Zhu Peng, Xiao-Jun Gao, Shang Fan, Jiang-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(35)H(38)N(4)O(3), was prepared as a spiro­lactam ring formation of rhodamine dye for comparison with a ring-opened form. The xanthene ring system is approximately planar. The dihedral angles formed by the spiro­lactam and phenol rings with the xanthene ring system are 85.7 and 109.4°, respectively. Each of the mol­ecules in the crystal structure contains one intra­molecular O—H⋯N hydrogen bond, and they form inter­molecular N—H⋯O hydrogen-bonded chains along the [100] direction. Weak inter­molecular C—H⋯O hydrogen-bonding contacts connect the infinite chains via crystallographic inversion centres to form a two-dimensional network. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960358/ /pubmed/21201431 http://dx.doi.org/10.1107/S1600536807068742 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Zhang, Li-Zhu
Peng, Xiao-Jun
Gao, Shang
Fan, Jiang-Li
[(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol
title [(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol
title_full [(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol
title_fullStr [(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol
title_full_unstemmed [(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol
title_short [(2-{[3′,6′-Bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1H-isoindole-1,9′-9H-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol
title_sort [(2-{[3′,6′-bis(ethyl­amino)-2′,7′-dimethyl-3-oxospiro­[1h-isoindole-1,9′-9h-xanthen]-2-yl}eth­yl)amino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960358/
https://www.ncbi.nlm.nih.gov/pubmed/21201431
http://dx.doi.org/10.1107/S1600536807068742
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