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Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base
The title compound, C(15)H(6)F(8)N(2), possesses a non-crystallographic twofold axis. The dihedral angle between the two benzene rings is 98.4 (2)°. The crystal structure involves intermolecular C—H⋯F hydrogen bonds.
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960364/ https://www.ncbi.nlm.nih.gov/pubmed/21201557 http://dx.doi.org/10.1107/S1600536808002602 |
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| author | Vande Velde, Christophe M. L. Didier, Delphine Blockhuys, Frank Sergeyev, Sergey |
| author_facet | Vande Velde, Christophe M. L. Didier, Delphine Blockhuys, Frank Sergeyev, Sergey |
| author_sort | Vande Velde, Christophe M. L. |
| collection | PubMed |
| description | The title compound, C(15)H(6)F(8)N(2), possesses a non-crystallographic twofold axis. The dihedral angle between the two benzene rings is 98.4 (2)°. The crystal structure involves intermolecular C—H⋯F hydrogen bonds. |
| format | Text |
| id | pubmed-2960364 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29603642010-12-30 Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base Vande Velde, Christophe M. L. Didier, Delphine Blockhuys, Frank Sergeyev, Sergey Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(6)F(8)N(2), possesses a non-crystallographic twofold axis. The dihedral angle between the two benzene rings is 98.4 (2)°. The crystal structure involves intermolecular C—H⋯F hydrogen bonds. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960364/ /pubmed/21201557 http://dx.doi.org/10.1107/S1600536808002602 Text en © Vande Velde et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Vande Velde, Christophe M. L. Didier, Delphine Blockhuys, Frank Sergeyev, Sergey Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base |
| title | Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base |
| title_full | Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base |
| title_fullStr | Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base |
| title_full_unstemmed | Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base |
| title_short | Racemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base |
| title_sort | racemic 1,2,3,4,7,8,9,10-octafluoro-6h,12h-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of tröger’s base |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960364/ https://www.ncbi.nlm.nih.gov/pubmed/21201557 http://dx.doi.org/10.1107/S1600536808002602 |
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