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Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)}

In the title compound, [Cu(2)(C(8)H(11)N(2)O(3)S)(2)Cl(2)], the Cu atoms are five-coordinated in a distorted square-pyramidal geometry by three donor atoms of the deprotonated anionic 2-(2-pyridylmethyl­amino)ethanesulfonate (pmt) ligand and two Cl atoms. The Cl atoms bridge two Cu atoms, giving a b...

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Detalles Bibliográficos
Autores principales: Du, Zhong-Xiang, Qin, Jian-Hua, Wang, Jian-Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960365/
https://www.ncbi.nlm.nih.gov/pubmed/21201304
http://dx.doi.org/10.1107/S1600536808000779
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author Du, Zhong-Xiang
Qin, Jian-Hua
Wang, Jian-Ge
author_facet Du, Zhong-Xiang
Qin, Jian-Hua
Wang, Jian-Ge
author_sort Du, Zhong-Xiang
collection PubMed
description In the title compound, [Cu(2)(C(8)H(11)N(2)O(3)S)(2)Cl(2)], the Cu atoms are five-coordinated in a distorted square-pyramidal geometry by three donor atoms of the deprotonated anionic 2-(2-pyridylmethyl­amino)ethanesulfonate (pmt) ligand and two Cl atoms. The Cl atoms bridge two Cu atoms, giving a binuclear structure; the centroid of the Cu(2)Cl(2) ring lies on a crystallographic center of inversion. The complex is stabilized by hydrogen bonds and π–π stacking inter­actions [average inter­planar distance = 3.4969 (1) Å and ring-centroid separation distance = 4.1068 (4) Å].
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spelling pubmed-29603652010-12-30 Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)} Du, Zhong-Xiang Qin, Jian-Hua Wang, Jian-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(8)H(11)N(2)O(3)S)(2)Cl(2)], the Cu atoms are five-coordinated in a distorted square-pyramidal geometry by three donor atoms of the deprotonated anionic 2-(2-pyridylmethyl­amino)ethanesulfonate (pmt) ligand and two Cl atoms. The Cl atoms bridge two Cu atoms, giving a binuclear structure; the centroid of the Cu(2)Cl(2) ring lies on a crystallographic center of inversion. The complex is stabilized by hydrogen bonds and π–π stacking inter­actions [average inter­planar distance = 3.4969 (1) Å and ring-centroid separation distance = 4.1068 (4) Å]. International Union of Crystallography 2008-01-11 /pmc/articles/PMC2960365/ /pubmed/21201304 http://dx.doi.org/10.1107/S1600536808000779 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Du, Zhong-Xiang
Qin, Jian-Hua
Wang, Jian-Ge
Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)}
title Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)}
title_full Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)}
title_fullStr Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)}
title_full_unstemmed Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)}
title_short Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) N,N′,O]copper(II)}
title_sort di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ(3) n,n′,o]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960365/
https://www.ncbi.nlm.nih.gov/pubmed/21201304
http://dx.doi.org/10.1107/S1600536808000779
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