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Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3) N,N′,O]copper(II)}
In the title compound, [Cu(2)(C(8)H(11)N(2)O(3)S)(2)Cl(2)], the Cu atoms are five-coordinated in a distorted square-pyramidal geometry by three donor atoms of the deprotonated anionic 2-(2-pyridylmethylamino)ethanesulfonate (pmt) ligand and two Cl atoms. The Cl atoms bridge two Cu atoms, giving a b...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960365/ https://www.ncbi.nlm.nih.gov/pubmed/21201304 http://dx.doi.org/10.1107/S1600536808000779 |
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author | Du, Zhong-Xiang Qin, Jian-Hua Wang, Jian-Ge |
author_facet | Du, Zhong-Xiang Qin, Jian-Hua Wang, Jian-Ge |
author_sort | Du, Zhong-Xiang |
collection | PubMed |
description | In the title compound, [Cu(2)(C(8)H(11)N(2)O(3)S)(2)Cl(2)], the Cu atoms are five-coordinated in a distorted square-pyramidal geometry by three donor atoms of the deprotonated anionic 2-(2-pyridylmethylamino)ethanesulfonate (pmt) ligand and two Cl atoms. The Cl atoms bridge two Cu atoms, giving a binuclear structure; the centroid of the Cu(2)Cl(2) ring lies on a crystallographic center of inversion. The complex is stabilized by hydrogen bonds and π–π stacking interactions [average interplanar distance = 3.4969 (1) Å and ring-centroid separation distance = 4.1068 (4) Å]. |
format | Text |
id | pubmed-2960365 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29603652010-12-30 Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3) N,N′,O]copper(II)} Du, Zhong-Xiang Qin, Jian-Hua Wang, Jian-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(8)H(11)N(2)O(3)S)(2)Cl(2)], the Cu atoms are five-coordinated in a distorted square-pyramidal geometry by three donor atoms of the deprotonated anionic 2-(2-pyridylmethylamino)ethanesulfonate (pmt) ligand and two Cl atoms. The Cl atoms bridge two Cu atoms, giving a binuclear structure; the centroid of the Cu(2)Cl(2) ring lies on a crystallographic center of inversion. The complex is stabilized by hydrogen bonds and π–π stacking interactions [average interplanar distance = 3.4969 (1) Å and ring-centroid separation distance = 4.1068 (4) Å]. International Union of Crystallography 2008-01-11 /pmc/articles/PMC2960365/ /pubmed/21201304 http://dx.doi.org/10.1107/S1600536808000779 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Du, Zhong-Xiang Qin, Jian-Hua Wang, Jian-Ge Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3) N,N′,O]copper(II)} |
title | Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3)
N,N′,O]copper(II)} |
title_full | Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3)
N,N′,O]copper(II)} |
title_fullStr | Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3)
N,N′,O]copper(II)} |
title_full_unstemmed | Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3)
N,N′,O]copper(II)} |
title_short | Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3)
N,N′,O]copper(II)} |
title_sort | di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ(3)
n,n′,o]copper(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960365/ https://www.ncbi.nlm.nih.gov/pubmed/21201304 http://dx.doi.org/10.1107/S1600536808000779 |
work_keys_str_mv | AT duzhongxiang dimchloridobis22pyridylmethylaminoethanesulfonatok3nnocopperii AT qinjianhua dimchloridobis22pyridylmethylaminoethanesulfonatok3nnocopperii AT wangjiange dimchloridobis22pyridylmethylaminoethanesulfonatok3nnocopperii |