Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate

In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa­hedral geometry. Three water mol­ecules, with occupancies of 1.0, 0.5 and 0....

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Detalles Bibliográficos
Autores principales: Kai, Zhao, Yin, Xian-Hong, Yu, Feng, Zhu, Jie, Lin, Cui-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960373/
https://www.ncbi.nlm.nih.gov/pubmed/21201375
http://dx.doi.org/10.1107/S1600536808002444
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author Kai, Zhao
Yin, Xian-Hong
Yu, Feng
Zhu, Jie
Lin, Cui-Wu
author_facet Kai, Zhao
Yin, Xian-Hong
Yu, Feng
Zhu, Jie
Lin, Cui-Wu
author_sort Kai, Zhao
collection PubMed
description In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa­hedral geometry. Three water mol­ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit. The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29603732010-12-30 Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate Kai, Zhao Yin, Xian-Hong Yu, Feng Zhu, Jie Lin, Cui-Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa­hedral geometry. Three water mol­ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit. The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960373/ /pubmed/21201375 http://dx.doi.org/10.1107/S1600536808002444 Text en © Kai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kai, Zhao
Yin, Xian-Hong
Yu, Feng
Zhu, Jie
Lin, Cui-Wu
Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate
title Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate
title_full Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate
title_fullStr Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate
title_full_unstemmed Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate
title_short Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(2) N (1),O (2)]cadmium(II) 1.75-hydrate
title_sort bis[6-(3,5-dimethyl-1h-pyrazol-1-yl)picolinato-κ(2) n (1),o (2)]cadmium(ii) 1.75-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960373/
https://www.ncbi.nlm.nih.gov/pubmed/21201375
http://dx.doi.org/10.1107/S1600536808002444
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