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Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)
The crystal structure of the title compound, [Ni(2)Cd(C(17)H(16)N(2)O(2))(2)(C(2)H(3)O(2))(2)(C(3)H(7)NO)(2)], contains discrete centrosymmetric hetero-trinuclear molecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD(2−) [N,N′-bis(salicylidene)-1,3-propanediaminate] a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960377/ https://www.ncbi.nlm.nih.gov/pubmed/21201269 http://dx.doi.org/10.1107/S1600536807067724 |
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author | Tatar Yıldırım, Leyla Atakol, Orhan |
author_facet | Tatar Yıldırım, Leyla Atakol, Orhan |
author_sort | Tatar Yıldırım, Leyla |
collection | PubMed |
description | The crystal structure of the title compound, [Ni(2)Cd(C(17)H(16)N(2)O(2))(2)(C(2)H(3)O(2))(2)(C(3)H(7)NO)(2)], contains discrete centrosymmetric hetero-trinuclear molecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD(2−) [N,N′-bis(salicylidene)-1,3-propanediaminate] and acetate ligands. The central Cd(II) ion is in a distorted octahedral coordination environment formed by four O atoms from two SALPD(2−) ligands in the equatorial plane and two O atoms of two symmetry-related acetate ligands in the axial positions. The symmetry-related Ni(II) ions are in slightly distorted octahedral environments, coordinated by two O and two N atoms from tetradendate SALPD(2−) ligands in the equatorial plane, while the axial positions are occupied by O atoms from a dimethylformamide and an acetate ligand. This results in the formation of three edge-shared octahedra in which the Ni⋯Cd distance is 3.1482 (15) Å. The crystal structure is stabilized by weak C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2960377 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29603772010-12-30 Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) Tatar Yıldırım, Leyla Atakol, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Ni(2)Cd(C(17)H(16)N(2)O(2))(2)(C(2)H(3)O(2))(2)(C(3)H(7)NO)(2)], contains discrete centrosymmetric hetero-trinuclear molecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD(2−) [N,N′-bis(salicylidene)-1,3-propanediaminate] and acetate ligands. The central Cd(II) ion is in a distorted octahedral coordination environment formed by four O atoms from two SALPD(2−) ligands in the equatorial plane and two O atoms of two symmetry-related acetate ligands in the axial positions. The symmetry-related Ni(II) ions are in slightly distorted octahedral environments, coordinated by two O and two N atoms from tetradendate SALPD(2−) ligands in the equatorial plane, while the axial positions are occupied by O atoms from a dimethylformamide and an acetate ligand. This results in the formation of three edge-shared octahedra in which the Ni⋯Cd distance is 3.1482 (15) Å. The crystal structure is stabilized by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960377/ /pubmed/21201269 http://dx.doi.org/10.1107/S1600536807067724 Text en © Tatar Yıldırım and Atakol 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tatar Yıldırım, Leyla Atakol, Orhan Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) |
title | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4)
O,N,N′,O′:2κ(2)
O,O′;2κ(2)
O,O′:3κ(4)
O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) |
title_full | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4)
O,N,N′,O′:2κ(2)
O,O′;2κ(2)
O,O′:3κ(4)
O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) |
title_fullStr | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4)
O,N,N′,O′:2κ(2)
O,O′;2κ(2)
O,O′:3κ(4)
O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) |
title_full_unstemmed | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4)
O,N,N′,O′:2κ(2)
O,O′;2κ(2)
O,O′:3κ(4)
O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) |
title_short | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis(N,N′-dimethylformamide)-1κO,3κO-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4)
O,N,N′,O′:2κ(2)
O,O′;2κ(2)
O,O′:3κ(4)
O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) |
title_sort | di-μ(2)-acetato-1:2κ(2)
o:o′;2:3κ(2)
o:o′-bis(n,n′-dimethylformamide)-1κo,3κo-bis{μ(2)-2,2′-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ(4)
o,n,n′,o′:2κ(2)
o,o′;2κ(2)
o,o′:3κ(4)
o,n,n′,o′-1,3-dinickel(ii)-2-cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960377/ https://www.ncbi.nlm.nih.gov/pubmed/21201269 http://dx.doi.org/10.1107/S1600536807067724 |
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