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Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)

The crystal structure of the title compound, [Ni(2)Cd(C(17)H(16)N(2)O(2))(2)(C(2)H(3)O(2))(2)(C(3)H(7)NO)(2)], contains discrete centrosymmetric hetero-trinuclear mol­ecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD(2−) [N,N′-bis­(salicyl­idene)-1,3-propane­diaminate] a...

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Detalles Bibliográficos
Autores principales: Tatar Yıldırım, Leyla, Atakol, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960377/
https://www.ncbi.nlm.nih.gov/pubmed/21201269
http://dx.doi.org/10.1107/S1600536807067724
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author Tatar Yıldırım, Leyla
Atakol, Orhan
author_facet Tatar Yıldırım, Leyla
Atakol, Orhan
author_sort Tatar Yıldırım, Leyla
collection PubMed
description The crystal structure of the title compound, [Ni(2)Cd(C(17)H(16)N(2)O(2))(2)(C(2)H(3)O(2))(2)(C(3)H(7)NO)(2)], contains discrete centrosymmetric hetero-trinuclear mol­ecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD(2−) [N,N′-bis­(salicyl­idene)-1,3-propane­diaminate] and acetate ligands. The central Cd(II) ion is in a distorted octa­hedral coordination environment formed by four O atoms from two SALPD(2−) ligands in the equatorial plane and two O atoms of two symmetry-related acetate ligands in the axial positions. The symmetry-related Ni(II) ions are in slightly distorted octa­hedral environments, coordinated by two O and two N atoms from tetra­dendate SALPD(2−) ligands in the equatorial plane, while the axial positions are occupied by O atoms from a dimethyl­formamide and an acetate ligand. This results in the formation of three edge-shared octa­hedra in which the Ni⋯Cd distance is 3.1482 (15) Å. The crystal structure is stabilized by weak C—H⋯O hydrogen bonds.
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spelling pubmed-29603772010-12-30 Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II) Tatar Yıldırım, Leyla Atakol, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Ni(2)Cd(C(17)H(16)N(2)O(2))(2)(C(2)H(3)O(2))(2)(C(3)H(7)NO)(2)], contains discrete centrosymmetric hetero-trinuclear mol­ecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD(2−) [N,N′-bis­(salicyl­idene)-1,3-propane­diaminate] and acetate ligands. The central Cd(II) ion is in a distorted octa­hedral coordination environment formed by four O atoms from two SALPD(2−) ligands in the equatorial plane and two O atoms of two symmetry-related acetate ligands in the axial positions. The symmetry-related Ni(II) ions are in slightly distorted octa­hedral environments, coordinated by two O and two N atoms from tetra­dendate SALPD(2−) ligands in the equatorial plane, while the axial positions are occupied by O atoms from a dimethyl­formamide and an acetate ligand. This results in the formation of three edge-shared octa­hedra in which the Ni⋯Cd distance is 3.1482 (15) Å. The crystal structure is stabilized by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960377/ /pubmed/21201269 http://dx.doi.org/10.1107/S1600536807067724 Text en © Tatar Yıldırım and Atakol 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tatar Yıldırım, Leyla
Atakol, Orhan
Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)
title Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)
title_full Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)
title_fullStr Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)
title_full_unstemmed Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)
title_short Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­(N,N′-dimethyl­formamide)-1κO,3κO-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) O,N,N′,O′:2κ(2) O,O′;2κ(2) O,O′:3κ(4) O,N,N′,O′-1,3-dinickel(II)-2-cadmium(II)
title_sort di-μ(2)-acetato-1:2κ(2) o:o′;2:3κ(2) o:o′-bis­(n,n′-dimethyl­formamide)-1κo,3κo-bis­{μ(2)-2,2′-[propane-1,3-diylbis(imino­methyl­ene)]diphenolato-1κ(4) o,n,n′,o′:2κ(2) o,o′;2κ(2) o,o′:3κ(4) o,n,n′,o′-1,3-dinickel(ii)-2-cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960377/
https://www.ncbi.nlm.nih.gov/pubmed/21201269
http://dx.doi.org/10.1107/S1600536807067724
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