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[μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]

The title complex, [Cu(2)(C(22)H(20)Br(2)N(4)O(2))(ClO(4))(2)], was prepared by the condensation of 2,6-diformyl-4-bromo­phenol with 1,3-diamino­propane in the presence of copper(II) ions. The macrocyclic ligand shows an approximately planar structure except for the two propene groups in the macrocy...

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Detalles Bibliográficos
Autores principales: Zhang, Han-Ping, Zhu, Jin-Xia, Zhou, Hong, Pan, Zhi-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960380/
https://www.ncbi.nlm.nih.gov/pubmed/21201303
http://dx.doi.org/10.1107/S1600536808000354
Descripción
Sumario:The title complex, [Cu(2)(C(22)H(20)Br(2)N(4)O(2))(ClO(4))(2)], was prepared by the condensation of 2,6-diformyl-4-bromo­phenol with 1,3-diamino­propane in the presence of copper(II) ions. The macrocyclic ligand shows an approximately planar structure except for the two propene groups in the macrocycle. The coordination polyhedron of each Cu atom can be described as distorted square pyramidal. The two Cu atoms are bridged by two phenolate O atoms of the macrocycle, with a Cu⋯Cu distance of 3.109 (2) Å.