[μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]

The title complex, [Cu(2)(C(22)H(20)Br(2)N(4)O(2))(ClO(4))(2)], was prepared by the condensation of 2,6-diformyl-4-bromo­phenol with 1,3-diamino­propane in the presence of copper(II) ions. The macrocyclic ligand shows an approximately planar structure except for the two propene groups in the macrocy...

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Detalles Bibliográficos
Autores principales: Zhang, Han-Ping, Zhu, Jin-Xia, Zhou, Hong, Pan, Zhi-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960380/
https://www.ncbi.nlm.nih.gov/pubmed/21201303
http://dx.doi.org/10.1107/S1600536808000354
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author Zhang, Han-Ping
Zhu, Jin-Xia
Zhou, Hong
Pan, Zhi-Quan
author_facet Zhang, Han-Ping
Zhu, Jin-Xia
Zhou, Hong
Pan, Zhi-Quan
author_sort Zhang, Han-Ping
collection PubMed
description The title complex, [Cu(2)(C(22)H(20)Br(2)N(4)O(2))(ClO(4))(2)], was prepared by the condensation of 2,6-diformyl-4-bromo­phenol with 1,3-diamino­propane in the presence of copper(II) ions. The macrocyclic ligand shows an approximately planar structure except for the two propene groups in the macrocycle. The coordination polyhedron of each Cu atom can be described as distorted square pyramidal. The two Cu atoms are bridged by two phenolate O atoms of the macrocycle, with a Cu⋯Cu distance of 3.109 (2) Å.
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spelling pubmed-29603802010-12-30 [μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)] Zhang, Han-Ping Zhu, Jin-Xia Zhou, Hong Pan, Zhi-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(22)H(20)Br(2)N(4)O(2))(ClO(4))(2)], was prepared by the condensation of 2,6-diformyl-4-bromo­phenol with 1,3-diamino­propane in the presence of copper(II) ions. The macrocyclic ligand shows an approximately planar structure except for the two propene groups in the macrocycle. The coordination polyhedron of each Cu atom can be described as distorted square pyramidal. The two Cu atoms are bridged by two phenolate O atoms of the macrocycle, with a Cu⋯Cu distance of 3.109 (2) Å. International Union of Crystallography 2008-01-11 /pmc/articles/PMC2960380/ /pubmed/21201303 http://dx.doi.org/10.1107/S1600536808000354 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Han-Ping
Zhu, Jin-Xia
Zhou, Hong
Pan, Zhi-Quan
[μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]
title [μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]
title_full [μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]
title_fullStr [μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]
title_full_unstemmed [μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]
title_short [μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]
title_sort [μ-11,23-dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) n (3),n (7),o,o′:κ(4) o,o′,n (15),n (19)]bis[perchloratocopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960380/
https://www.ncbi.nlm.nih.gov/pubmed/21201303
http://dx.doi.org/10.1107/S1600536808000354
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