Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]

In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolate (L) ligands and one pyridine (py) mol­ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a trident...

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Detalles Bibliográficos
Autores principales: Yang, Chun, Yan, Ou-Yang, Wang, Qing-Lun, Liao, Dai-Zheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960381/
https://www.ncbi.nlm.nih.gov/pubmed/21201321
http://dx.doi.org/10.1107/S1600536808000962
Descripción
Sumario:In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolate (L) ligands and one pyridine (py) mol­ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by π–π inter­actions between adjacent pyridine mol­ecules, with a centroid–centroid distance of 3.724 Å, resulting in a two-dimensional structure.

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