Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]

In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolate (L) ligands and one pyridine (py) mol­ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a trident...

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Detalles Bibliográficos
Autores principales: Yang, Chun, Yan, Ou-Yang, Wang, Qing-Lun, Liao, Dai-Zheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960381/
https://www.ncbi.nlm.nih.gov/pubmed/21201321
http://dx.doi.org/10.1107/S1600536808000962
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author Yang, Chun
Yan, Ou-Yang
Wang, Qing-Lun
Liao, Dai-Zheng
author_facet Yang, Chun
Yan, Ou-Yang
Wang, Qing-Lun
Liao, Dai-Zheng
author_sort Yang, Chun
collection PubMed
description In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolate (L) ligands and one pyridine (py) mol­ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by π–π inter­actions between adjacent pyridine mol­ecules, with a centroid–centroid distance of 3.724 Å, resulting in a two-dimensional structure.
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spelling pubmed-29603812010-12-30 Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)] Yang, Chun Yan, Ou-Yang Wang, Qing-Lun Liao, Dai-Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolate (L) ligands and one pyridine (py) mol­ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by π–π inter­actions between adjacent pyridine mol­ecules, with a centroid–centroid distance of 3.724 Å, resulting in a two-dimensional structure. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960381/ /pubmed/21201321 http://dx.doi.org/10.1107/S1600536808000962 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Yang, Chun
Yan, Ou-Yang
Wang, Qing-Lun
Liao, Dai-Zheng
Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]
title Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]
title_full Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]
title_fullStr Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]
title_full_unstemmed Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]
title_short Bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) O,N,O′}bis­[(pyridine-κN)zinc(II)]
title_sort bis{μ-2-[(2-oxidobenzyl­idene)amino­meth­yl]phenolato-κ(3) o,n,o′}bis­[(pyridine-κn)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960381/
https://www.ncbi.nlm.nih.gov/pubmed/21201321
http://dx.doi.org/10.1107/S1600536808000962
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AT wangqinglun bism22oxidobenzylideneaminomethylphenolatok3onobispyridineknzincii
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