Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate

In the title compound, [Ti(C(16)H(18)N(4))(2)]·C(4)H(8)O, the Ti(IV) ion is chelated by two Schiff base dianions with a TiN(8) distorted square-anti­prismatic coordination geometry. The two cyclo­hexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal struc...

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Detalles Bibliográficos
Autores principales: Zhang, Xue-Qin, Xu, Bin, Li, Ya-Hong, Li, Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960382/
https://www.ncbi.nlm.nih.gov/pubmed/21201378
http://dx.doi.org/10.1107/S1600536808002870
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author Zhang, Xue-Qin
Xu, Bin
Li, Ya-Hong
Li, Wu
author_facet Zhang, Xue-Qin
Xu, Bin
Li, Ya-Hong
Li, Wu
author_sort Zhang, Xue-Qin
collection PubMed
description In the title compound, [Ti(C(16)H(18)N(4))(2)]·C(4)H(8)O, the Ti(IV) ion is chelated by two Schiff base dianions with a TiN(8) distorted square-anti­prismatic coordination geometry. The two cyclo­hexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal structure.
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spelling pubmed-29603822010-12-30 Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate Zhang, Xue-Qin Xu, Bin Li, Ya-Hong Li, Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ti(C(16)H(18)N(4))(2)]·C(4)H(8)O, the Ti(IV) ion is chelated by two Schiff base dianions with a TiN(8) distorted square-anti­prismatic coordination geometry. The two cyclo­hexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal structure. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960382/ /pubmed/21201378 http://dx.doi.org/10.1107/S1600536808002870 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xue-Qin
Xu, Bin
Li, Ya-Hong
Li, Wu
Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate
title Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate
title_full Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate
title_fullStr Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate
title_full_unstemmed Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate
title_short Bis[N,N′-bis­[(1H-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(IV) tetra­hydro­furan solvate
title_sort bis[n,n′-bis­[(1h-pyrrol-2-yl)methyl­ene]cyclo­hexane-1,2-diamine]titanium(iv) tetra­hydro­furan solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960382/
https://www.ncbi.nlm.nih.gov/pubmed/21201378
http://dx.doi.org/10.1107/S1600536808002870
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