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l-Glutamic acid hydro­chloride at 153 K

The title compound [systematic name: (S)-1,3-dicarboxy­propanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (197...

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Detalles Bibliográficos
Autores principales: Zhang, Yi Jian, Shu, Zhan, Xu, Wei, Chen, Gang, Li, Zu-Guang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960383/
https://www.ncbi.nlm.nih.gov/pubmed/21201473
http://dx.doi.org/10.1107/S1600536807068560
Descripción
Sumario:The title compound [systematic name: (S)-1,3-dicarboxy­propanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (1972). B28, 2514–2519] using neutron diffraction with R = 0.043. The present determination at 153 K has R = 0.017 and all the H atoms are located. There are obvious differences in some C—C bond lengths between the present and previous studies. In the present structure, l-glutamic acid is protonated and is linked to the Cl(−) anion by an O—H⋯Cl hydrogen bond. The crystal structure is established by a three-dimensional network of O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds.