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l-Glutamic acid hydrochloride at 153 K
The title compound [systematic name: (S)-1,3-dicarboxypropanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (197...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960383/ https://www.ncbi.nlm.nih.gov/pubmed/21201473 http://dx.doi.org/10.1107/S1600536807068560 |
Sumario: | The title compound [systematic name: (S)-1,3-dicarboxypropanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (1972). B28, 2514–2519] using neutron diffraction with R = 0.043. The present determination at 153 K has R = 0.017 and all the H atoms are located. There are obvious differences in some C—C bond lengths between the present and previous studies. In the present structure, l-glutamic acid is protonated and is linked to the Cl(−) anion by an O—H⋯Cl hydrogen bond. The crystal structure is established by a three-dimensional network of O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds. |
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