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l-Glutamic acid hydro­chloride at 153 K

The title compound [systematic name: (S)-1,3-dicarboxy­propanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (197...

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Autores principales: Zhang, Yi Jian, Shu, Zhan, Xu, Wei, Chen, Gang, Li, Zu-Guang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960383/
https://www.ncbi.nlm.nih.gov/pubmed/21201473
http://dx.doi.org/10.1107/S1600536807068560
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author Zhang, Yi Jian
Shu, Zhan
Xu, Wei
Chen, Gang
Li, Zu-Guang
author_facet Zhang, Yi Jian
Shu, Zhan
Xu, Wei
Chen, Gang
Li, Zu-Guang
author_sort Zhang, Yi Jian
collection PubMed
description The title compound [systematic name: (S)-1,3-dicarboxy­propanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (1972). B28, 2514–2519] using neutron diffraction with R = 0.043. The present determination at 153 K has R = 0.017 and all the H atoms are located. There are obvious differences in some C—C bond lengths between the present and previous studies. In the present structure, l-glutamic acid is protonated and is linked to the Cl(−) anion by an O—H⋯Cl hydrogen bond. The crystal structure is established by a three-dimensional network of O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds.
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spelling pubmed-29603832010-12-30 l-Glutamic acid hydro­chloride at 153 K Zhang, Yi Jian Shu, Zhan Xu, Wei Chen, Gang Li, Zu-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: (S)-1,3-dicarboxy­propanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (1972). B28, 2514–2519] using neutron diffraction with R = 0.043. The present determination at 153 K has R = 0.017 and all the H atoms are located. There are obvious differences in some C—C bond lengths between the present and previous studies. In the present structure, l-glutamic acid is protonated and is linked to the Cl(−) anion by an O—H⋯Cl hydrogen bond. The crystal structure is established by a three-dimensional network of O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960383/ /pubmed/21201473 http://dx.doi.org/10.1107/S1600536807068560 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Zhang, Yi Jian
Shu, Zhan
Xu, Wei
Chen, Gang
Li, Zu-Guang
l-Glutamic acid hydro­chloride at 153 K
title l-Glutamic acid hydro­chloride at 153 K
title_full l-Glutamic acid hydro­chloride at 153 K
title_fullStr l-Glutamic acid hydro­chloride at 153 K
title_full_unstemmed l-Glutamic acid hydro­chloride at 153 K
title_short l-Glutamic acid hydro­chloride at 153 K
title_sort l-glutamic acid hydro­chloride at 153 k
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960383/
https://www.ncbi.nlm.nih.gov/pubmed/21201473
http://dx.doi.org/10.1107/S1600536807068560
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