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l-Glutamic acid hydrochloride at 153 K
The title compound [systematic name: (S)-1,3-dicarboxypropanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (197...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960383/ https://www.ncbi.nlm.nih.gov/pubmed/21201473 http://dx.doi.org/10.1107/S1600536807068560 |
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author | Zhang, Yi Jian Shu, Zhan Xu, Wei Chen, Gang Li, Zu-Guang |
author_facet | Zhang, Yi Jian Shu, Zhan Xu, Wei Chen, Gang Li, Zu-Guang |
author_sort | Zhang, Yi Jian |
collection | PubMed |
description | The title compound [systematic name: (S)-1,3-dicarboxypropanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (1972). B28, 2514–2519] using neutron diffraction with R = 0.043. The present determination at 153 K has R = 0.017 and all the H atoms are located. There are obvious differences in some C—C bond lengths between the present and previous studies. In the present structure, l-glutamic acid is protonated and is linked to the Cl(−) anion by an O—H⋯Cl hydrogen bond. The crystal structure is established by a three-dimensional network of O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds. |
format | Text |
id | pubmed-2960383 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29603832010-12-30 l-Glutamic acid hydrochloride at 153 K Zhang, Yi Jian Shu, Zhan Xu, Wei Chen, Gang Li, Zu-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: (S)-1,3-dicarboxypropanaminium chloride], C(5)H(10)NO(4) (+)·Cl(−), has been investigated previously by Dawson [Acta Cryst. (1953). 6, 81–83], with R = 0.106 and without the location of H atoms, and then by Sequeira, Rajagopal & Chidambaram [Acta Cryst. (1972). B28, 2514–2519] using neutron diffraction with R = 0.043. The present determination at 153 K has R = 0.017 and all the H atoms are located. There are obvious differences in some C—C bond lengths between the present and previous studies. In the present structure, l-glutamic acid is protonated and is linked to the Cl(−) anion by an O—H⋯Cl hydrogen bond. The crystal structure is established by a three-dimensional network of O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960383/ /pubmed/21201473 http://dx.doi.org/10.1107/S1600536807068560 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Zhang, Yi Jian Shu, Zhan Xu, Wei Chen, Gang Li, Zu-Guang l-Glutamic acid hydrochloride at 153 K |
title |
l-Glutamic acid hydrochloride at 153 K |
title_full |
l-Glutamic acid hydrochloride at 153 K |
title_fullStr |
l-Glutamic acid hydrochloride at 153 K |
title_full_unstemmed |
l-Glutamic acid hydrochloride at 153 K |
title_short |
l-Glutamic acid hydrochloride at 153 K |
title_sort | l-glutamic acid hydrochloride at 153 k |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960383/ https://www.ncbi.nlm.nih.gov/pubmed/21201473 http://dx.doi.org/10.1107/S1600536807068560 |
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