(Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II)

The title structure, [Zn(SeO(4))(CH(4)N(2)S)(3)], is isomorphous with sulfatotris(thio­urea)zinc(II). In both structures, the Zn(2+) cation is coordinated in a tetra­hedral geometry. The corresponding intra­molecular distances are quite similar except for the Se—O and S—O distances. Although the hyd...

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Autores principales: Krupková, Radmila, Fábry, Jan, Císařová, Ivana, Vaněk, Přemysl
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960388/
https://www.ncbi.nlm.nih.gov/pubmed/21201305
http://dx.doi.org/10.1107/S1600536808000743
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author Krupková, Radmila
Fábry, Jan
Císařová, Ivana
Vaněk, Přemysl
author_facet Krupková, Radmila
Fábry, Jan
Císařová, Ivana
Vaněk, Přemysl
author_sort Krupková, Radmila
collection PubMed
description The title structure, [Zn(SeO(4))(CH(4)N(2)S)(3)], is isomorphous with sulfatotris(thio­urea)zinc(II). In both structures, the Zn(2+) cation is coordinated in a tetra­hedral geometry. The corresponding intra­molecular distances are quite similar except for the Se—O and S—O distances. Although the hydrogen-bonding patterns are similar, there are some differences; in the title structure all the H atoms are involved in the hydrogen-bond pattern, in contrast to the situation in sulfatotris(thio­urea)zinc(II). No reproducible anomalies were detected by differential scanning calorimetry in the range 93–463 K until decomposition started at the higher temperature.
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spelling pubmed-29603882010-12-30 (Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II) Krupková, Radmila Fábry, Jan Císařová, Ivana Vaněk, Přemysl Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title structure, [Zn(SeO(4))(CH(4)N(2)S)(3)], is isomorphous with sulfatotris(thio­urea)zinc(II). In both structures, the Zn(2+) cation is coordinated in a tetra­hedral geometry. The corresponding intra­molecular distances are quite similar except for the Se—O and S—O distances. Although the hydrogen-bonding patterns are similar, there are some differences; in the title structure all the H atoms are involved in the hydrogen-bond pattern, in contrast to the situation in sulfatotris(thio­urea)zinc(II). No reproducible anomalies were detected by differential scanning calorimetry in the range 93–463 K until decomposition started at the higher temperature. International Union of Crystallography 2008-01-11 /pmc/articles/PMC2960388/ /pubmed/21201305 http://dx.doi.org/10.1107/S1600536808000743 Text en © Krupková et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Krupková, Radmila
Fábry, Jan
Císařová, Ivana
Vaněk, Přemysl
(Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II)
title (Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II)
title_full (Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II)
title_fullStr (Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II)
title_full_unstemmed (Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II)
title_short (Tetra­oxidoselenato-κO)tris­(thio­urea-κS)zinc(II)
title_sort (tetra­oxidoselenato-κo)tris­(thio­urea-κs)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960388/
https://www.ncbi.nlm.nih.gov/pubmed/21201305
http://dx.doi.org/10.1107/S1600536808000743
work_keys_str_mv AT krupkovaradmila tetraoxidoselenatokotristhioureakszincii
AT fabryjan tetraoxidoselenatokotristhioureakszincii
AT cisarovaivana tetraoxidoselenatokotristhioureakszincii
AT vanekpremysl tetraoxidoselenatokotristhioureakszincii

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