{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate

In the title complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)CO-CH(3), the Cu(II) atom is four-coordinated in a square-planar geometry by two O atoms and two N atoms of the deprotonated Schiff base. The Sm(III) atom is ten-coordinate, chelated by three nitrate groups and linked to the four O atom...

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Detalles Bibliográficos
Autores principales: Wang, Jing-Hua, Gao, Po, Yan, Peng-Fei, Li, Guang-Ming, Hou, Guang-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960389/
https://www.ncbi.nlm.nih.gov/pubmed/21201306
http://dx.doi.org/10.1107/S1600536807061454
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author Wang, Jing-Hua
Gao, Po
Yan, Peng-Fei
Li, Guang-Ming
Hou, Guang-Feng
author_facet Wang, Jing-Hua
Gao, Po
Yan, Peng-Fei
Li, Guang-Ming
Hou, Guang-Feng
author_sort Wang, Jing-Hua
collection PubMed
description In the title complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)CO-CH(3), the Cu(II) atom is four-coordinated in a square-planar geometry by two O atoms and two N atoms of the deprotonated Schiff base. The Sm(III) atom is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base.
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spelling pubmed-29603892010-12-30 {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate Wang, Jing-Hua Gao, Po Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)CO-CH(3), the Cu(II) atom is four-coordinated in a square-planar geometry by two O atoms and two N atoms of the deprotonated Schiff base. The Sm(III) atom is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960389/ /pubmed/21201306 http://dx.doi.org/10.1107/S1600536807061454 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wang, Jing-Hua
Gao, Po
Yan, Peng-Fei
Li, Guang-Ming
Hou, Guang-Feng
{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate
title {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate
title_full {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate
title_fullStr {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate
title_full_unstemmed {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate
title_short {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(II)samarium(III) acetone solvate
title_sort {μ-6,6′-dimeth­oxy-2,2′-[propane-1,3-diyl­bis(nitrilo­methyl­idyne)]­diphenolato}­trinitratocopper(ii)samarium(iii) acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960389/
https://www.ncbi.nlm.nih.gov/pubmed/21201306
http://dx.doi.org/10.1107/S1600536807061454
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