Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine

The title compound, [Yb(2)(CF(3)O(3)S)(C(10)H(15))(2)(OH)(2)(C(12)H(12)N(2))(2)](C(24)H(20)B)·C(12)H(12)N(2), crystallizes as a half-sandwich complex with a bridging trifluoro­methane­sulfonate as well as two bridging hydroxide groups. The bound bipyridine ligands have N—C—C—N torsion angles of 13.1...

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Autor principal: Kazhdan, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960390/
https://www.ncbi.nlm.nih.gov/pubmed/21201376
http://dx.doi.org/10.1107/S1600536808002791
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author Kazhdan, Daniel
author_facet Kazhdan, Daniel
author_sort Kazhdan, Daniel
collection PubMed
description The title compound, [Yb(2)(CF(3)O(3)S)(C(10)H(15))(2)(OH)(2)(C(12)H(12)N(2))(2)](C(24)H(20)B)·C(12)H(12)N(2), crystallizes as a half-sandwich complex with a bridging trifluoro­methane­sulfonate as well as two bridging hydroxide groups. The bound bipyridine ligands have N—C—C—N torsion angles of 13.1 (9) and −12.1 (8)°. The structure also contains an uncoordinated 5,5′-dimethyl-2,2′-bipyridine molecule with an N—C—C—N torsion angle of 169.5 (7)°. The triply bridged Yb centers are 3.5990 (4) Å apart. The Yb—N bond lengths are in the range 2.389 (6)–2.424 (5) Å.
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spelling pubmed-29603902010-12-30 Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine Kazhdan, Daniel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Yb(2)(CF(3)O(3)S)(C(10)H(15))(2)(OH)(2)(C(12)H(12)N(2))(2)](C(24)H(20)B)·C(12)H(12)N(2), crystallizes as a half-sandwich complex with a bridging trifluoro­methane­sulfonate as well as two bridging hydroxide groups. The bound bipyridine ligands have N—C—C—N torsion angles of 13.1 (9) and −12.1 (8)°. The structure also contains an uncoordinated 5,5′-dimethyl-2,2′-bipyridine molecule with an N—C—C—N torsion angle of 169.5 (7)°. The triply bridged Yb centers are 3.5990 (4) Å apart. The Yb—N bond lengths are in the range 2.389 (6)–2.424 (5) Å. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960390/ /pubmed/21201376 http://dx.doi.org/10.1107/S1600536808002791 Text en © Daniel Kazhdan 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kazhdan, Daniel
Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine
title Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine
title_full Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine
title_fullStr Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine
title_full_unstemmed Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine
title_short Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine
title_sort di-μ-hydroxido-κ(4) o:o-μ-trifluoro­methane­sulfonato-κ(2) o:o′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) n,n′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(iii)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960390/
https://www.ncbi.nlm.nih.gov/pubmed/21201376
http://dx.doi.org/10.1107/S1600536808002791
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