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Di-μ-hydroxido-κ(4) O:O-μ-trifluoro­methane­sulfonato-κ(2) O:O′-bis­[(5,5′-dimethyl-2,2-bipyridine-κ(2) N,N′)(η(5)-penta­methyl­cyclo­penta­dien­yl)ytterbium(III)] tetra­phenyl­borate 5,5′-dimethyl-2,2-bipyridine

The title compound, [Yb(2)(CF(3)O(3)S)(C(10)H(15))(2)(OH)(2)(C(12)H(12)N(2))(2)](C(24)H(20)B)·C(12)H(12)N(2), crystallizes as a half-sandwich complex with a bridging trifluoro­methane­sulfonate as well as two bridging hydroxide groups. The bound bipyridine ligands have N—C—C—N torsion angles of 13.1...

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Detalles Bibliográficos
Autor principal: Kazhdan, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960390/
https://www.ncbi.nlm.nih.gov/pubmed/21201376
http://dx.doi.org/10.1107/S1600536808002791