[4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate

In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(−)·0.5H(2)O, there are inter­molecular O—H⋯Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl­phosphonium moiety are at angles of 59.73 (15), 79.15...

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Detalles Bibliográficos
Autores principales: Nazir, Saba, Khawar Rauf, M., Ebihara, Masahiro, Hameed, Shahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960404/
https://www.ncbi.nlm.nih.gov/pubmed/21201450
http://dx.doi.org/10.1107/S1600536808000184
Descripción
Sumario:In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(−)·0.5H(2)O, there are inter­molecular O—H⋯Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl­phosphonium moiety are at angles of 59.73 (15), 79.15 (14) and 82.81 (17)° with the C/P/C planes.

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