[4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate

In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(−)·0.5H(2)O, there are inter­molecular O—H⋯Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl­phosphonium moiety are at angles of 59.73 (15), 79.15...

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Detalles Bibliográficos
Autores principales: Nazir, Saba, Khawar Rauf, M., Ebihara, Masahiro, Hameed, Shahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960404/
https://www.ncbi.nlm.nih.gov/pubmed/21201450
http://dx.doi.org/10.1107/S1600536808000184
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author Nazir, Saba
Khawar Rauf, M.
Ebihara, Masahiro
Hameed, Shahid
author_facet Nazir, Saba
Khawar Rauf, M.
Ebihara, Masahiro
Hameed, Shahid
author_sort Nazir, Saba
collection PubMed
description In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(−)·0.5H(2)O, there are inter­molecular O—H⋯Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl­phosphonium moiety are at angles of 59.73 (15), 79.15 (14) and 82.81 (17)° with the C/P/C planes.
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spelling pubmed-29604042010-12-30 [4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate Nazir, Saba Khawar Rauf, M. Ebihara, Masahiro Hameed, Shahid Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(−)·0.5H(2)O, there are inter­molecular O—H⋯Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl­phosphonium moiety are at angles of 59.73 (15), 79.15 (14) and 82.81 (17)° with the C/P/C planes. International Union of Crystallography 2008-01-11 /pmc/articles/PMC2960404/ /pubmed/21201450 http://dx.doi.org/10.1107/S1600536808000184 Text en © Nazir et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nazir, Saba
Khawar Rauf, M.
Ebihara, Masahiro
Hameed, Shahid
[4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate
title [4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate
title_full [4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate
title_fullStr [4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate
title_full_unstemmed [4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate
title_short [4-(Methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate
title_sort [4-(methoxy­carbon­yl)benz­yl]triphenyl­phospho­nium bromide hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960404/
https://www.ncbi.nlm.nih.gov/pubmed/21201450
http://dx.doi.org/10.1107/S1600536808000184
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AT khawarraufm 4methoxycarbonylbenzyltriphenylphosphoniumbromidehemihydrate
AT ebiharamasahiro 4methoxycarbonylbenzyltriphenylphosphoniumbromidehemihydrate
AT hameedshahid 4methoxycarbonylbenzyltriphenylphosphoniumbromidehemihydrate

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