Cargando…

catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]

Hexamethyl­phospho­ramide (hmp), tetra­thio­tungstate(VI), silver sulfide and lanthanum(III) nitrate are self-assembled to form discrete cations one-dimensional poylmeric anionic chains [AgWS(4)](n)(n) (−) in the title compound, {[La(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central La atom i...

Descripción completa

Detalles Bibliográficos
Autores principales: Tang, Guodong, Zhang, Jinfang, Zhang, Chi, Lu, Lude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960413/
https://www.ncbi.nlm.nih.gov/pubmed/21201349
http://dx.doi.org/10.1107/S1600536807066597
_version_ 1782188733702864896
author Tang, Guodong
Zhang, Jinfang
Zhang, Chi
Lu, Lude
author_facet Tang, Guodong
Zhang, Jinfang
Zhang, Chi
Lu, Lude
author_sort Tang, Guodong
collection PubMed
description Hexamethyl­phospho­ramide (hmp), tetra­thio­tungstate(VI), silver sulfide and lanthanum(III) nitrate are self-assembled to form discrete cations one-dimensional poylmeric anionic chains [AgWS(4)](n)(n) (−) in the title compound, {[La(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central La atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain with W⋯Ag⋯W and Ag⋯W⋯Ag angles of 165.94 (3) and 155.894 (14)° presents a distorted linear configuration. Five N atoms, 18 C atoms and their attached H atoms are disordered equally over two positions.
format Text
id pubmed-2960413
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29604132010-12-30 catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] Tang, Guodong Zhang, Jinfang Zhang, Chi Lu, Lude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hexamethyl­phospho­ramide (hmp), tetra­thio­tungstate(VI), silver sulfide and lanthanum(III) nitrate are self-assembled to form discrete cations one-dimensional poylmeric anionic chains [AgWS(4)](n)(n) (−) in the title compound, {[La(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central La atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain with W⋯Ag⋯W and Ag⋯W⋯Ag angles of 165.94 (3) and 155.894 (14)° presents a distorted linear configuration. Five N atoms, 18 C atoms and their attached H atoms are disordered equally over two positions. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960413/ /pubmed/21201349 http://dx.doi.org/10.1107/S1600536807066597 Text en © Tang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Guodong
Zhang, Jinfang
Zhang, Chi
Lu, Lude
catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]
title catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]
title_full catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]
title_fullStr catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]
title_full_unstemmed catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]
title_short catena-Poly[[tetra­kis(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]
title_sort catena-poly[[tetra­kis(hexa­methyl­phospho­ramide-κo)bis­(nitrato-κ(2) o,o′)lanthanum(iii)] [silver(i)-di-μ(2)-sulfido-tungstate(vi)-di-μ(2)-sulfido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960413/
https://www.ncbi.nlm.nih.gov/pubmed/21201349
http://dx.doi.org/10.1107/S1600536807066597
work_keys_str_mv AT tangguodong catenapolytetrakishexamethylphosphoramidekobisnitratok2oolanthanumiiisilveridim2sulfidotungstatevidim2sulfido
AT zhangjinfang catenapolytetrakishexamethylphosphoramidekobisnitratok2oolanthanumiiisilveridim2sulfidotungstatevidim2sulfido
AT zhangchi catenapolytetrakishexamethylphosphoramidekobisnitratok2oolanthanumiiisilveridim2sulfidotungstatevidim2sulfido
AT lulude catenapolytetrakishexamethylphosphoramidekobisnitratok2oolanthanumiiisilveridim2sulfidotungstatevidim2sulfido