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catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]]
Hexamethylphosphoramide (hmp), tetrathiotungstate(VI), silver sulfide and lanthanum(III) nitrate are self-assembled to form discrete cations one-dimensional poylmeric anionic chains [AgWS(4)](n)(n) (−) in the title compound, {[La(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central La atom i...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960413/ https://www.ncbi.nlm.nih.gov/pubmed/21201349 http://dx.doi.org/10.1107/S1600536807066597 |
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author | Tang, Guodong Zhang, Jinfang Zhang, Chi Lu, Lude |
author_facet | Tang, Guodong Zhang, Jinfang Zhang, Chi Lu, Lude |
author_sort | Tang, Guodong |
collection | PubMed |
description | Hexamethylphosphoramide (hmp), tetrathiotungstate(VI), silver sulfide and lanthanum(III) nitrate are self-assembled to form discrete cations one-dimensional poylmeric anionic chains [AgWS(4)](n)(n) (−) in the title compound, {[La(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central La atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain with W⋯Ag⋯W and Ag⋯W⋯Ag angles of 165.94 (3) and 155.894 (14)° presents a distorted linear configuration. Five N atoms, 18 C atoms and their attached H atoms are disordered equally over two positions. |
format | Text |
id | pubmed-2960413 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604132010-12-30 catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] Tang, Guodong Zhang, Jinfang Zhang, Chi Lu, Lude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hexamethylphosphoramide (hmp), tetrathiotungstate(VI), silver sulfide and lanthanum(III) nitrate are self-assembled to form discrete cations one-dimensional poylmeric anionic chains [AgWS(4)](n)(n) (−) in the title compound, {[La(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central La atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain with W⋯Ag⋯W and Ag⋯W⋯Ag angles of 165.94 (3) and 155.894 (14)° presents a distorted linear configuration. Five N atoms, 18 C atoms and their attached H atoms are disordered equally over two positions. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960413/ /pubmed/21201349 http://dx.doi.org/10.1107/S1600536807066597 Text en © Tang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tang, Guodong Zhang, Jinfang Zhang, Chi Lu, Lude catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] |
title |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] |
title_full |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] |
title_fullStr |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] |
title_full_unstemmed |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] |
title_short |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]] |
title_sort | catena-poly[[tetrakis(hexamethylphosphoramide-κo)bis(nitrato-κ(2)
o,o′)lanthanum(iii)] [silver(i)-di-μ(2)-sulfido-tungstate(vi)-di-μ(2)-sulfido]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960413/ https://www.ncbi.nlm.nih.gov/pubmed/21201349 http://dx.doi.org/10.1107/S1600536807066597 |
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