Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate

In the title heterotrinuclear coordination compound, [CaCu(2)(C(9)H(4)NO(5))(2)(C(3)H(4)N(2))(2)(H(2)O)(3)]·7H(2)O, the Ca(2+) cation is in a penta­gonal–bipyramidal geometry and bridges two (1H-imidazole)[2-(oxaloamino)benzoato(3−)]copper(II) units in its equatorial plane. Each Cu(II) atom has a no...

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Detalles Bibliográficos
Autores principales: Mei, Chongzhen, Li, Kaihui, Zhang, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960417/
https://www.ncbi.nlm.nih.gov/pubmed/21201260
http://dx.doi.org/10.1107/S1600536807067517
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author Mei, Chongzhen
Li, Kaihui
Zhang, Peng
author_facet Mei, Chongzhen
Li, Kaihui
Zhang, Peng
author_sort Mei, Chongzhen
collection PubMed
description In the title heterotrinuclear coordination compound, [CaCu(2)(C(9)H(4)NO(5))(2)(C(3)H(4)N(2))(2)(H(2)O)(3)]·7H(2)O, the Ca(2+) cation is in a penta­gonal–bipyramidal geometry and bridges two (1H-imidazole)[2-(oxaloamino)benzoato(3−)]copper(II) units in its equatorial plane. Each Cu(II) atom has a normal square-planar geometry. The mol­ecule has approximate local (non-crystallographic) mirror symmetry and 23 classical hydrogen bonds are found in the crystal structure.
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spelling pubmed-29604172010-12-30 Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate Mei, Chongzhen Li, Kaihui Zhang, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title heterotrinuclear coordination compound, [CaCu(2)(C(9)H(4)NO(5))(2)(C(3)H(4)N(2))(2)(H(2)O)(3)]·7H(2)O, the Ca(2+) cation is in a penta­gonal–bipyramidal geometry and bridges two (1H-imidazole)[2-(oxaloamino)benzoato(3−)]copper(II) units in its equatorial plane. Each Cu(II) atom has a normal square-planar geometry. The mol­ecule has approximate local (non-crystallographic) mirror symmetry and 23 classical hydrogen bonds are found in the crystal structure. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960417/ /pubmed/21201260 http://dx.doi.org/10.1107/S1600536807067517 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Mei, Chongzhen
Li, Kaihui
Zhang, Peng
Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate
title Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate
title_full Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate
title_fullStr Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate
title_full_unstemmed Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate
title_short Triaqua­bis(1H-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(II)calcium(II) hepta­hydrate
title_sort triaqua­bis(1h-imidazole)bis­[μ(2)-2-(oxalo­amino)benzoato(3−)]dicopper(ii)calcium(ii) hepta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960417/
https://www.ncbi.nlm.nih.gov/pubmed/21201260
http://dx.doi.org/10.1107/S1600536807067517
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AT zhangpeng triaquabis1himidazolebism22oxaloaminobenzoato3dicopperiicalciumiiheptahydrate

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