Bis[N-(8-quinol­yl)pyridine-2-carbox­amidato-κ(3) N,N′,N′′]manganese(III) perchlorate monohydrate

The Mn(III) ion in the title complex, [Mn(C(15)H(10)N(3)O)(2)]ClO(4)·H(2)O, is coordinated meridionally by six N atoms from two tridentate N-(8-quinol­yl)pyridine-2-carboxamidate ligands, yielding a distorted octa­hedral coordination geometry. The two ligands are nearly planar and their mean planes...

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Detalles Bibliográficos
Autores principales: Meng, Qingguo, Wang, Lintong, Liu, Yanzhen, Pang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960422/
https://www.ncbi.nlm.nih.gov/pubmed/21201298
http://dx.doi.org/10.1107/S1600536808000287
Descripción
Sumario:The Mn(III) ion in the title complex, [Mn(C(15)H(10)N(3)O)(2)]ClO(4)·H(2)O, is coordinated meridionally by six N atoms from two tridentate N-(8-quinol­yl)pyridine-2-carboxamidate ligands, yielding a distorted octa­hedral coordination geometry. The two ligands are nearly planar and their mean planes are almost perpendicular, with a dihedral angle of 86.7 (2)°.

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