Cargando…
(Acetylacetonato-κ(2) O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3) O,N,O′]manganese(III)
The Mn(III) atom in the title complex, [Mn(C(13)H(9)N(3)O(2))(C(5)H(7)O(2))(H(2)O)], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetylacetonate anion and a water molecule in a distorted octahedral geometry. There is an extended tw...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960424/ https://www.ncbi.nlm.nih.gov/pubmed/21201327 http://dx.doi.org/10.1107/S1600536807060734 |
| _version_ | 1782188736401899520 |
|---|---|
| author | Wang, Zeng-You Liu, Shi-Xiong Fu, Zhong-Wu |
| author_facet | Wang, Zeng-You Liu, Shi-Xiong Fu, Zhong-Wu |
| author_sort | Wang, Zeng-You |
| collection | PubMed |
| description | The Mn(III) atom in the title complex, [Mn(C(13)H(9)N(3)O(2))(C(5)H(7)O(2))(H(2)O)], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetylacetonate anion and a water molecule in a distorted octahedral geometry. There is an extended two-dimensional supramolecular motif resulting from O—H⋯N hydrogen bonds between the coordinated water molecule and a hydrazine N or pyridine N atom, and from C—H⋯O hydrogen bonds between a CH group and the phenolate O atom. |
| format | Text |
| id | pubmed-2960424 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29604242010-12-30 (Acetylacetonato-κ(2) O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3) O,N,O′]manganese(III) Wang, Zeng-You Liu, Shi-Xiong Fu, Zhong-Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(III) atom in the title complex, [Mn(C(13)H(9)N(3)O(2))(C(5)H(7)O(2))(H(2)O)], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetylacetonate anion and a water molecule in a distorted octahedral geometry. There is an extended two-dimensional supramolecular motif resulting from O—H⋯N hydrogen bonds between the coordinated water molecule and a hydrazine N or pyridine N atom, and from C—H⋯O hydrogen bonds between a CH group and the phenolate O atom. International Union of Crystallography 2008-01-18 /pmc/articles/PMC2960424/ /pubmed/21201327 http://dx.doi.org/10.1107/S1600536807060734 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Wang, Zeng-You Liu, Shi-Xiong Fu, Zhong-Wu (Acetylacetonato-κ(2) O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3) O,N,O′]manganese(III) |
| title | (Acetylacetonato-κ(2)
O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3)
O,N,O′]manganese(III) |
| title_full | (Acetylacetonato-κ(2)
O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3)
O,N,O′]manganese(III) |
| title_fullStr | (Acetylacetonato-κ(2)
O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3)
O,N,O′]manganese(III) |
| title_full_unstemmed | (Acetylacetonato-κ(2)
O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3)
O,N,O′]manganese(III) |
| title_short | (Acetylacetonato-κ(2)
O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3)
O,N,O′]manganese(III) |
| title_sort | (acetylacetonato-κ(2)
o,o′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ(3)
o,n,o′]manganese(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960424/ https://www.ncbi.nlm.nih.gov/pubmed/21201327 http://dx.doi.org/10.1107/S1600536807060734 |
| work_keys_str_mv | AT wangzengyou acetylacetonatok2ooaquasalicylaldehydenicotinoylhydrazonato2k3onomanganeseiii AT liushixiong acetylacetonatok2ooaquasalicylaldehydenicotinoylhydrazonato2k3onomanganeseiii AT fuzhongwu acetylacetonatok2ooaquasalicylaldehydenicotinoylhydrazonato2k3onomanganeseiii |