Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)]

The title compound, [Mn(2)(C(18)H(18)N(2)O(2))(2)Cl(2)], was synthesized by the reaction between manganese(II) o-chloro­benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxy­acetophenone. The centrosymmetric dimer contains two Jahn–Teller-distorted ma...

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Detalles Bibliográficos
Autores principales: Thampidas, V. S., Radhakrishnan, T., Pike, Robert D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960426/
https://www.ncbi.nlm.nih.gov/pubmed/21201280
http://dx.doi.org/10.1107/S1600536808000226
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author Thampidas, V. S.
Radhakrishnan, T.
Pike, Robert D.
author_facet Thampidas, V. S.
Radhakrishnan, T.
Pike, Robert D.
author_sort Thampidas, V. S.
collection PubMed
description The title compound, [Mn(2)(C(18)H(18)N(2)O(2))(2)Cl(2)], was synthesized by the reaction between manganese(II) o-chloro­benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxy­acetophenone. The centrosymmetric dimer contains two Jahn–Teller-distorted mangan­ese(III) ions, each in an octa­hedral geometry, connected through two phen­oxy bridges from two ligands.
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spelling pubmed-29604262010-12-30 Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)] Thampidas, V. S. Radhakrishnan, T. Pike, Robert D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(2)(C(18)H(18)N(2)O(2))(2)Cl(2)], was synthesized by the reaction between manganese(II) o-chloro­benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxy­acetophenone. The centrosymmetric dimer contains two Jahn–Teller-distorted mangan­ese(III) ions, each in an octa­hedral geometry, connected through two phen­oxy bridges from two ligands. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960426/ /pubmed/21201280 http://dx.doi.org/10.1107/S1600536808000226 Text en © Thampidas et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Thampidas, V. S.
Radhakrishnan, T.
Pike, Robert D.
Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)]
title Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)]
title_full Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)]
title_fullStr Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)]
title_full_unstemmed Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)]
title_short Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) O,N,N′,O′:O}bis­[chloridomanganese(III)]
title_sort bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethyl­idyne]diphenolato-κ(5) o,n,n′,o′:o}bis­[chloridomanganese(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960426/
https://www.ncbi.nlm.nih.gov/pubmed/21201280
http://dx.doi.org/10.1107/S1600536808000226
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AT radhakrishnant bism2211ethane12diyldinitrilodiethylidynediphenolatok5onnoobischloridomanganeseiii
AT pikerobertd bism2211ethane12diyldinitrilodiethylidynediphenolatok5onnoobischloridomanganeseiii

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