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μ-Pyrazine-2,5-dicarboxyl­ato-bis­[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate

A new tert-butanol solvate of [{((i)PrC(6)H(4)Me)RuCl}(2){μ-2,5-pyz(COO)(2)}] (pyz = pyrazine) has been crystallized and structurally characterized. The solvate, [Ru(2)(C(10)H(14))(2)(C(6)H(2)N(2)O(4))Cl(2)]·2C(4)H(10)O, contains one half-mol­ecule of the ruthenium(II) complex and one mol­ecule of t...

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Detalles Bibliográficos
Autores principales: Sanchez Ballester, Noelia M., Elsegood, Mark R. J., Smith, Martin B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960433/
https://www.ncbi.nlm.nih.gov/pubmed/21201282
http://dx.doi.org/10.1107/S1600536808000202
Descripción
Sumario:A new tert-butanol solvate of [{((i)PrC(6)H(4)Me)RuCl}(2){μ-2,5-pyz(COO)(2)}] (pyz = pyrazine) has been crystallized and structurally characterized. The solvate, [Ru(2)(C(10)H(14))(2)(C(6)H(2)N(2)O(4))Cl(2)]·2C(4)H(10)O, contains one half-mol­ecule of the ruthenium(II) complex and one mol­ecule of tert-butanol in the asymmetric unit. The complex mol­ecule lies on an inversion centre with the two chlorides trans. In contrast, the previously reported structure was solvent-free. Similar metric parameters are found between the butanol solvate and the solvent-free form and an inter­molecular O—H⋯O hydrogen bond exists between μ-pyrazine-2,5-dicarboxyl­ato-bis­[chlorido(η(6)-p-cymene)­ruthenium(II)] and the tert-butanol mol­ecule.