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μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate
A new tert-butanol solvate of [{((i)PrC(6)H(4)Me)RuCl}(2){μ-2,5-pyz(COO)(2)}] (pyz = pyrazine) has been crystallized and structurally characterized. The solvate, [Ru(2)(C(10)H(14))(2)(C(6)H(2)N(2)O(4))Cl(2)]·2C(4)H(10)O, contains one half-molecule of the ruthenium(II) complex and one molecule of t...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960433/ https://www.ncbi.nlm.nih.gov/pubmed/21201282 http://dx.doi.org/10.1107/S1600536808000202 |
| _version_ | 1782188738506391552 |
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| author | Sanchez Ballester, Noelia M. Elsegood, Mark R. J. Smith, Martin B. |
| author_facet | Sanchez Ballester, Noelia M. Elsegood, Mark R. J. Smith, Martin B. |
| author_sort | Sanchez Ballester, Noelia M. |
| collection | PubMed |
| description | A new tert-butanol solvate of [{((i)PrC(6)H(4)Me)RuCl}(2){μ-2,5-pyz(COO)(2)}] (pyz = pyrazine) has been crystallized and structurally characterized. The solvate, [Ru(2)(C(10)H(14))(2)(C(6)H(2)N(2)O(4))Cl(2)]·2C(4)H(10)O, contains one half-molecule of the ruthenium(II) complex and one molecule of tert-butanol in the asymmetric unit. The complex molecule lies on an inversion centre with the two chlorides trans. In contrast, the previously reported structure was solvent-free. Similar metric parameters are found between the butanol solvate and the solvent-free form and an intermolecular O—H⋯O hydrogen bond exists between μ-pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] and the tert-butanol molecule. |
| format | Text |
| id | pubmed-2960433 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29604332010-12-30 μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate Sanchez Ballester, Noelia M. Elsegood, Mark R. J. Smith, Martin B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A new tert-butanol solvate of [{((i)PrC(6)H(4)Me)RuCl}(2){μ-2,5-pyz(COO)(2)}] (pyz = pyrazine) has been crystallized and structurally characterized. The solvate, [Ru(2)(C(10)H(14))(2)(C(6)H(2)N(2)O(4))Cl(2)]·2C(4)H(10)O, contains one half-molecule of the ruthenium(II) complex and one molecule of tert-butanol in the asymmetric unit. The complex molecule lies on an inversion centre with the two chlorides trans. In contrast, the previously reported structure was solvent-free. Similar metric parameters are found between the butanol solvate and the solvent-free form and an intermolecular O—H⋯O hydrogen bond exists between μ-pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] and the tert-butanol molecule. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960433/ /pubmed/21201282 http://dx.doi.org/10.1107/S1600536808000202 Text en © Sanchez Ballester et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sanchez Ballester, Noelia M. Elsegood, Mark R. J. Smith, Martin B. μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate |
| title | μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate |
| title_full | μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate |
| title_fullStr | μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate |
| title_full_unstemmed | μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate |
| title_short | μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(II)] tert-butanol disolvate |
| title_sort | μ-pyrazine-2,5-dicarboxylato-bis[chlorido(η(6)-p-cymene)ruthenium(ii)] tert-butanol disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960433/ https://www.ncbi.nlm.nih.gov/pubmed/21201282 http://dx.doi.org/10.1107/S1600536808000202 |
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