4-Amino­phenyl­sulfur penta­fluoride

In the title compound, C(6)H(6)F(5)NS, the environment of the S atom is roughly octa­hedral. The axial F—S bond appears slightly elongated with respect to the four equatorial F—S bonds. Equatorial F atoms are staggered with respect to the benzene ring. The N atom is displaced from the benzene plane...

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Detalles Bibliográficos
Autores principales: Nava, Eva Lina, Jesih, Adolf, Goreshnik, Evgeny
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960437/
https://www.ncbi.nlm.nih.gov/pubmed/21201443
http://dx.doi.org/10.1107/S160053680800024X
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author Nava, Eva Lina
Jesih, Adolf
Goreshnik, Evgeny
author_facet Nava, Eva Lina
Jesih, Adolf
Goreshnik, Evgeny
author_sort Nava, Eva Lina
collection PubMed
description In the title compound, C(6)H(6)F(5)NS, the environment of the S atom is roughly octa­hedral. The axial F—S bond appears slightly elongated with respect to the four equatorial F—S bonds. Equatorial F atoms are staggered with respect to the benzene ring. The N atom is displaced from the benzene plane by 0.154 (4) Å. The F—S—C—C torsion angles differ greatly from the values observed in the related structure of 4-acetamido­phenyl­sulfur penta­fluoride. The packing is stabil­ized by weak N—H⋯F contacts.
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spelling pubmed-29604372010-12-30 4-Amino­phenyl­sulfur penta­fluoride Nava, Eva Lina Jesih, Adolf Goreshnik, Evgeny Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(6)F(5)NS, the environment of the S atom is roughly octa­hedral. The axial F—S bond appears slightly elongated with respect to the four equatorial F—S bonds. Equatorial F atoms are staggered with respect to the benzene ring. The N atom is displaced from the benzene plane by 0.154 (4) Å. The F—S—C—C torsion angles differ greatly from the values observed in the related structure of 4-acetamido­phenyl­sulfur penta­fluoride. The packing is stabil­ized by weak N—H⋯F contacts. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960437/ /pubmed/21201443 http://dx.doi.org/10.1107/S160053680800024X Text en © Nava et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nava, Eva Lina
Jesih, Adolf
Goreshnik, Evgeny
4-Amino­phenyl­sulfur penta­fluoride
title 4-Amino­phenyl­sulfur penta­fluoride
title_full 4-Amino­phenyl­sulfur penta­fluoride
title_fullStr 4-Amino­phenyl­sulfur penta­fluoride
title_full_unstemmed 4-Amino­phenyl­sulfur penta­fluoride
title_short 4-Amino­phenyl­sulfur penta­fluoride
title_sort 4-amino­phenyl­sulfur penta­fluoride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960437/
https://www.ncbi.nlm.nih.gov/pubmed/21201443
http://dx.doi.org/10.1107/S160053680800024X
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