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Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate)
In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octahedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu—N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoroacetate...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960438/ https://www.ncbi.nlm.nih.gov/pubmed/21201328 http://dx.doi.org/10.1107/S1600536808001438 |
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author | Karpova, Elena V. Zakharov, Maxim A. Boltalin, Alexandr I. Rybakov, Victor B. |
author_facet | Karpova, Elena V. Zakharov, Maxim A. Boltalin, Alexandr I. Rybakov, Victor B. |
author_sort | Karpova, Elena V. |
collection | PubMed |
description | In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octahedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu—N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoroacetate anions are connected by weak N—H⋯O and N—H⋯F hydrogen bonds, forming a three-dimensional framework. In both anions, the F atoms are disordered over two positions; in one the site-occupancy factors are 0.55 and 0.45, in the other the values are 0.69 and 0.31. |
format | Text |
id | pubmed-2960438 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604382010-12-30 Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate) Karpova, Elena V. Zakharov, Maxim A. Boltalin, Alexandr I. Rybakov, Victor B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octahedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu—N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoroacetate anions are connected by weak N—H⋯O and N—H⋯F hydrogen bonds, forming a three-dimensional framework. In both anions, the F atoms are disordered over two positions; in one the site-occupancy factors are 0.55 and 0.45, in the other the values are 0.69 and 0.31. International Union of Crystallography 2008-01-18 /pmc/articles/PMC2960438/ /pubmed/21201328 http://dx.doi.org/10.1107/S1600536808001438 Text en © Karpova et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Karpova, Elena V. Zakharov, Maxim A. Boltalin, Alexandr I. Rybakov, Victor B. Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate) |
title | Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate) |
title_full | Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate) |
title_fullStr | Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate) |
title_full_unstemmed | Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate) |
title_short | Tris(ethane-1,2-diamine)copper(II) bis(trifluoroacetate) |
title_sort | tris(ethane-1,2-diamine)copper(ii) bis(trifluoroacetate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960438/ https://www.ncbi.nlm.nih.gov/pubmed/21201328 http://dx.doi.org/10.1107/S1600536808001438 |
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