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Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate)

In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octa­hedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu—N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoro­acetate...

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Detalles Bibliográficos
Autores principales: Karpova, Elena V., Zakharov, Maxim A., Boltalin, Alexandr I., Rybakov, Victor B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960438/
https://www.ncbi.nlm.nih.gov/pubmed/21201328
http://dx.doi.org/10.1107/S1600536808001438
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author Karpova, Elena V.
Zakharov, Maxim A.
Boltalin, Alexandr I.
Rybakov, Victor B.
author_facet Karpova, Elena V.
Zakharov, Maxim A.
Boltalin, Alexandr I.
Rybakov, Victor B.
author_sort Karpova, Elena V.
collection PubMed
description In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octa­hedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu—N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoro­acetate anions are connected by weak N—H⋯O and N—H⋯F hydrogen bonds, forming a three-dimensional framework. In both anions, the F atoms are disordered over two positions; in one the site-occupancy factors are 0.55 and 0.45, in the other the values are 0.69 and 0.31.
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spelling pubmed-29604382010-12-30 Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate) Karpova, Elena V. Zakharov, Maxim A. Boltalin, Alexandr I. Rybakov, Victor B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octa­hedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu—N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoro­acetate anions are connected by weak N—H⋯O and N—H⋯F hydrogen bonds, forming a three-dimensional framework. In both anions, the F atoms are disordered over two positions; in one the site-occupancy factors are 0.55 and 0.45, in the other the values are 0.69 and 0.31. International Union of Crystallography 2008-01-18 /pmc/articles/PMC2960438/ /pubmed/21201328 http://dx.doi.org/10.1107/S1600536808001438 Text en © Karpova et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Karpova, Elena V.
Zakharov, Maxim A.
Boltalin, Alexandr I.
Rybakov, Victor B.
Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate)
title Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate)
title_full Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate)
title_fullStr Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate)
title_full_unstemmed Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate)
title_short Tris(ethane-1,2-diamine)copper(II) bis­(trifluoro­acetate)
title_sort tris(ethane-1,2-diamine)copper(ii) bis­(trifluoro­acetate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960438/
https://www.ncbi.nlm.nih.gov/pubmed/21201328
http://dx.doi.org/10.1107/S1600536808001438
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