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4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1)
The crystal structure of the title compound, C(9)H(20)NO(+)·Cl(−)·0.33(H(3)O(+)·Cl(−)), is composed of 4-hydroxy-2,2,6,6-tetramethylpiperidinium cations, hydroxonium cations and chloride anions, which are connected via O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonding. The 4-hydroxy-2,2,6,6-tetramethyl...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960453/ https://www.ncbi.nlm.nih.gov/pubmed/21201531 http://dx.doi.org/10.1107/S1600536808002158 |
| _version_ | 1782188743241760768 |
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| author | Zhang, Li Zhang, Peng-Wei Wang, Xiao-Hui Chen, Li Shen, Qu-Fei |
| author_facet | Zhang, Li Zhang, Peng-Wei Wang, Xiao-Hui Chen, Li Shen, Qu-Fei |
| author_sort | Zhang, Li |
| collection | PubMed |
| description | The crystal structure of the title compound, C(9)H(20)NO(+)·Cl(−)·0.33(H(3)O(+)·Cl(−)), is composed of 4-hydroxy-2,2,6,6-tetramethylpiperidinium cations, hydroxonium cations and chloride anions, which are connected via O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonding. The 4-hydroxy-2,2,6,6-tetramethylpiperidinium cation and one of the two crystallographically independent chloride anions are located on a mirror plane. The hydroxonium cation is located on a threefold axis and the second crystallographically independent chloride anion is located on a sixfold rotoinversion axis. Due to symmetry, the hydroxonium cation is disordered over two positions.[Image: see text] |
| format | Text |
| id | pubmed-2960453 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29604532010-12-30 4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) Zhang, Li Zhang, Peng-Wei Wang, Xiao-Hui Chen, Li Shen, Qu-Fei Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(9)H(20)NO(+)·Cl(−)·0.33(H(3)O(+)·Cl(−)), is composed of 4-hydroxy-2,2,6,6-tetramethylpiperidinium cations, hydroxonium cations and chloride anions, which are connected via O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonding. The 4-hydroxy-2,2,6,6-tetramethylpiperidinium cation and one of the two crystallographically independent chloride anions are located on a mirror plane. The hydroxonium cation is located on a threefold axis and the second crystallographically independent chloride anion is located on a sixfold rotoinversion axis. Due to symmetry, the hydroxonium cation is disordered over two positions.[Image: see text] International Union of Crystallography 2008-01-25 /pmc/articles/PMC2960453/ /pubmed/21201531 http://dx.doi.org/10.1107/S1600536808002158 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Zhang, Li Zhang, Peng-Wei Wang, Xiao-Hui Chen, Li Shen, Qu-Fei 4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) |
| title | 4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) |
| title_full | 4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) |
| title_fullStr | 4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) |
| title_full_unstemmed | 4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) |
| title_short | 4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) |
| title_sort | 4-hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960453/ https://www.ncbi.nlm.nih.gov/pubmed/21201531 http://dx.doi.org/10.1107/S1600536808002158 |
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