Cargando…

A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II)

The title complex, [Co(C(8)H(12)N(2)O(3))(2)(C(3)H(4)N(2))(2)], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally...

Descripción completa

Detalles Bibliográficos
Autores principales: Fan, Run-Zhen, Hong, Peng-Zhi, Song, Wen-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960457/
https://www.ncbi.nlm.nih.gov/pubmed/21201267
http://dx.doi.org/10.1107/S1600536807067815
_version_ 1782188744230567936
author Fan, Run-Zhen
Hong, Peng-Zhi
Song, Wen-Dong
author_facet Fan, Run-Zhen
Hong, Peng-Zhi
Song, Wen-Dong
author_sort Fan, Run-Zhen
collection PubMed
description The title complex, [Co(C(8)H(12)N(2)O(3))(2)(C(3)H(4)N(2))(2)], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The mol­ecules are self-assembled via inter­molecular N—H⋯O hydrogen-bonding inter­actions into a supra­molecular network.
format Text
id pubmed-2960457
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29604572010-12-30 A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II) Fan, Run-Zhen Hong, Peng-Zhi Song, Wen-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(8)H(12)N(2)O(3))(2)(C(3)H(4)N(2))(2)], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The mol­ecules are self-assembled via inter­molecular N—H⋯O hydrogen-bonding inter­actions into a supra­molecular network. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960457/ /pubmed/21201267 http://dx.doi.org/10.1107/S1600536807067815 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Fan, Run-Zhen
Hong, Peng-Zhi
Song, Wen-Dong
A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II)
title A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II)
title_full A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II)
title_fullStr A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II)
title_full_unstemmed A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II)
title_short A redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(II)
title_sort redetermination of bis­(5,5′-diethyl­barbiturato)bis­(imidazole)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960457/
https://www.ncbi.nlm.nih.gov/pubmed/21201267
http://dx.doi.org/10.1107/S1600536807067815
work_keys_str_mv AT fanrunzhen aredeterminationofbis55diethylbarbituratobisimidazolecobaltii
AT hongpengzhi aredeterminationofbis55diethylbarbituratobisimidazolecobaltii
AT songwendong aredeterminationofbis55diethylbarbituratobisimidazolecobaltii
AT fanrunzhen redeterminationofbis55diethylbarbituratobisimidazolecobaltii
AT hongpengzhi redeterminationofbis55diethylbarbituratobisimidazolecobaltii
AT songwendong redeterminationofbis55diethylbarbituratobisimidazolecobaltii