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A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
The title complex, [Co(C(8)H(12)N(2)O(3))(2)(C(3)H(4)N(2))(2)], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960457/ https://www.ncbi.nlm.nih.gov/pubmed/21201267 http://dx.doi.org/10.1107/S1600536807067815 |
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author | Fan, Run-Zhen Hong, Peng-Zhi Song, Wen-Dong |
author_facet | Fan, Run-Zhen Hong, Peng-Zhi Song, Wen-Dong |
author_sort | Fan, Run-Zhen |
collection | PubMed |
description | The title complex, [Co(C(8)H(12)N(2)O(3))(2)(C(3)H(4)N(2))(2)], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The molecules are self-assembled via intermolecular N—H⋯O hydrogen-bonding interactions into a supramolecular network. |
format | Text |
id | pubmed-2960457 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604572010-12-30 A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II) Fan, Run-Zhen Hong, Peng-Zhi Song, Wen-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(8)H(12)N(2)O(3))(2)(C(3)H(4)N(2))(2)], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The molecules are self-assembled via intermolecular N—H⋯O hydrogen-bonding interactions into a supramolecular network. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960457/ /pubmed/21201267 http://dx.doi.org/10.1107/S1600536807067815 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Fan, Run-Zhen Hong, Peng-Zhi Song, Wen-Dong A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II) |
title | A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II) |
title_full | A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II) |
title_fullStr | A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II) |
title_full_unstemmed | A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II) |
title_short | A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II) |
title_sort | redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960457/ https://www.ncbi.nlm.nih.gov/pubmed/21201267 http://dx.doi.org/10.1107/S1600536807067815 |
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