N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine

The diphenyl­phosphine groups in the title compound, C(29)H(31)NP(2), are staggered relative to the PNP backbone. The N atom adopts an almost planar geometry with the two P atoms and the C atom attached to it, in order to accommodate the steric bulk of the phenyl groups and the alkyl group. Three C...

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Detalles Bibliográficos
Autores principales: Cloete, Nicoline, Visser, Hendrik G., Roodt, Andreas, Dixon, Jontho T., Blann, Kevin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960458/
https://www.ncbi.nlm.nih.gov/pubmed/21201505
http://dx.doi.org/10.1107/S1600536808001839
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author Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
Dixon, Jontho T.
Blann, Kevin
author_facet Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
Dixon, Jontho T.
Blann, Kevin
author_sort Cloete, Nicoline
collection PubMed
description The diphenyl­phosphine groups in the title compound, C(29)H(31)NP(2), are staggered relative to the PNP backbone. The N atom adopts an almost planar geometry with the two P atoms and the C atom attached to it, in order to accommodate the steric bulk of the phenyl groups and the alkyl group. Three C atoms of the 1,2-dimethylpropylamine group are disordered over two positions in a 9:1 ratio. The mol­ecules pack diagonally in the unit cell across the ac plane in a head-to-tail fashion.
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spelling pubmed-29604582010-12-30 N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine Cloete, Nicoline Visser, Hendrik G. Roodt, Andreas Dixon, Jontho T. Blann, Kevin Acta Crystallogr Sect E Struct Rep Online Organic Papers The diphenyl­phosphine groups in the title compound, C(29)H(31)NP(2), are staggered relative to the PNP backbone. The N atom adopts an almost planar geometry with the two P atoms and the C atom attached to it, in order to accommodate the steric bulk of the phenyl groups and the alkyl group. Three C atoms of the 1,2-dimethylpropylamine group are disordered over two positions in a 9:1 ratio. The mol­ecules pack diagonally in the unit cell across the ac plane in a head-to-tail fashion. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960458/ /pubmed/21201505 http://dx.doi.org/10.1107/S1600536808001839 Text en © Cloete et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
Dixon, Jontho T.
Blann, Kevin
N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine
title N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine
title_full N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine
title_fullStr N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine
title_full_unstemmed N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine
title_short N,N-Bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine
title_sort n,n-bis(diphenyl­phosphino)-1,2-dimethyl­propyl­amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960458/
https://www.ncbi.nlm.nih.gov/pubmed/21201505
http://dx.doi.org/10.1107/S1600536808001839
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AT visserhendrikg nnbisdiphenylphosphino12dimethylpropylamine
AT roodtandreas nnbisdiphenylphosphino12dimethylpropylamine
AT dixonjonthot nnbisdiphenylphosphino12dimethylpropylamine
AT blannkevin nnbisdiphenylphosphino12dimethylpropylamine

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