Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate

The title compound, C(12)H(14)O(6)S, is a dicarboxylic acid diethyl ester of 3,4-ethyl­enedioxy­thio­phene, which is a component of electrically conductive poly(3,4-ethyl­enedioxy­thio­phene) (PEDOT). The ethyl­ene group is disordered over two sites with occupancy factors 0.64 and 0.36. Both the car...

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Detalles Bibliográficos
Autores principales: Ono, Katsuhiko, Tomura, Masaaki, Saito, Katsuhiro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960460/
https://www.ncbi.nlm.nih.gov/pubmed/21201494
http://dx.doi.org/10.1107/S1600536808000937
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author Ono, Katsuhiko
Tomura, Masaaki
Saito, Katsuhiro
author_facet Ono, Katsuhiko
Tomura, Masaaki
Saito, Katsuhiro
author_sort Ono, Katsuhiko
collection PubMed
description The title compound, C(12)H(14)O(6)S, is a dicarboxylic acid diethyl ester of 3,4-ethyl­enedioxy­thio­phene, which is a component of electrically conductive poly(3,4-ethyl­enedioxy­thio­phene) (PEDOT). The ethyl­ene group is disordered over two sites with occupancy factors 0.64 and 0.36. Both the carbonyl groups are coplanar with the thio­phene ring. The mol­ecules form centrosymmetric dimers with an R (2) (2)(12) coupling by inter­molecular C—H⋯O hydrogen bonds [3.333 (5) Å] at the ethoxy­carbonyl groups. The dimer units are arranged to form a ribbon-like mol­ecular sheet.
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spelling pubmed-29604602010-12-30 Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate Ono, Katsuhiko Tomura, Masaaki Saito, Katsuhiro Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(14)O(6)S, is a dicarboxylic acid diethyl ester of 3,4-ethyl­enedioxy­thio­phene, which is a component of electrically conductive poly(3,4-ethyl­enedioxy­thio­phene) (PEDOT). The ethyl­ene group is disordered over two sites with occupancy factors 0.64 and 0.36. Both the carbonyl groups are coplanar with the thio­phene ring. The mol­ecules form centrosymmetric dimers with an R (2) (2)(12) coupling by inter­molecular C—H⋯O hydrogen bonds [3.333 (5) Å] at the ethoxy­carbonyl groups. The dimer units are arranged to form a ribbon-like mol­ecular sheet. International Union of Crystallography 2008-01-18 /pmc/articles/PMC2960460/ /pubmed/21201494 http://dx.doi.org/10.1107/S1600536808000937 Text en © Ono et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ono, Katsuhiko
Tomura, Masaaki
Saito, Katsuhiro
Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate
title Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate
title_full Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate
title_fullStr Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate
title_full_unstemmed Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate
title_short Diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate
title_sort diethyl 2,3-dihydro­thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960460/
https://www.ncbi.nlm.nih.gov/pubmed/21201494
http://dx.doi.org/10.1107/S1600536808000937
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AT tomuramasaaki diethyl23dihydrothieno34b14dioxine57dicarboxylate
AT saitokatsuhiro diethyl23dihydrothieno34b14dioxine57dicarboxylate

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