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Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)]
The reaction of strontium(II) nitrate with the proton-transfer compound (pdaH(2))(py-3,5-dc)·H(2)O (where pda = propane-1,3-diamine and py-3,5-dcH(2) = pyridine-3,5-dicarboxylic acid) leads to the formation of the title polymeric compound, [Sr(C(7)H(3)NO(4))(H(2)O)(4)](n). The propane-1,3-diaminium...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960463/ https://www.ncbi.nlm.nih.gov/pubmed/21201331 http://dx.doi.org/10.1107/S1600536808001335 |
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author | Aghabozorg, Hossein Nemati, Andya Derikvand, Zohreh Ghadermazi, Mohammad Daneshvar, Shirin |
author_facet | Aghabozorg, Hossein Nemati, Andya Derikvand, Zohreh Ghadermazi, Mohammad Daneshvar, Shirin |
author_sort | Aghabozorg, Hossein |
collection | PubMed |
description | The reaction of strontium(II) nitrate with the proton-transfer compound (pdaH(2))(py-3,5-dc)·H(2)O (where pda = propane-1,3-diamine and py-3,5-dcH(2) = pyridine-3,5-dicarboxylic acid) leads to the formation of the title polymeric compound, [Sr(C(7)H(3)NO(4))(H(2)O)(4)](n). The propane-1,3-diaminium cation is not incorporated in this crystal structure. The Sr(II) atom lies on an inversion centre and is eight-coordinated by four O atoms from three py-3,5-dc ligands and four O atoms from four coordinated water molecules. The coordination polyhedron of the Sr(II) atom is a distorted dodecahedron. These binuclear units are connected via the carboxylate O atoms to build a one-dimensional polymeric chain. In the crystal structure, non-covalant interactions consisting of hydrogen bonds (X—H⋯O, with X = O and C) and π–π stacking interactions [3.4604 (19) Å] connect the various components to form a supramolecular structure. |
format | Text |
id | pubmed-2960463 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604632010-12-30 Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)] Aghabozorg, Hossein Nemati, Andya Derikvand, Zohreh Ghadermazi, Mohammad Daneshvar, Shirin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of strontium(II) nitrate with the proton-transfer compound (pdaH(2))(py-3,5-dc)·H(2)O (where pda = propane-1,3-diamine and py-3,5-dcH(2) = pyridine-3,5-dicarboxylic acid) leads to the formation of the title polymeric compound, [Sr(C(7)H(3)NO(4))(H(2)O)(4)](n). The propane-1,3-diaminium cation is not incorporated in this crystal structure. The Sr(II) atom lies on an inversion centre and is eight-coordinated by four O atoms from three py-3,5-dc ligands and four O atoms from four coordinated water molecules. The coordination polyhedron of the Sr(II) atom is a distorted dodecahedron. These binuclear units are connected via the carboxylate O atoms to build a one-dimensional polymeric chain. In the crystal structure, non-covalant interactions consisting of hydrogen bonds (X—H⋯O, with X = O and C) and π–π stacking interactions [3.4604 (19) Å] connect the various components to form a supramolecular structure. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960463/ /pubmed/21201331 http://dx.doi.org/10.1107/S1600536808001335 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Aghabozorg, Hossein Nemati, Andya Derikvand, Zohreh Ghadermazi, Mohammad Daneshvar, Shirin Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)] |
title | Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)] |
title_full | Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)] |
title_fullStr | Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)] |
title_full_unstemmed | Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)] |
title_short | Poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(II)] |
title_sort | poly[tetraaqua-μ(3)-pyridine-3,5-dicarboxylato-strontium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960463/ https://www.ncbi.nlm.nih.gov/pubmed/21201331 http://dx.doi.org/10.1107/S1600536808001335 |
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