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(2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate
The title compound, C(27)H(30)O(6), was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960464/ https://www.ncbi.nlm.nih.gov/pubmed/21201549 http://dx.doi.org/10.1107/S1600536808002651 |
Sumario: | The title compound, C(27)H(30)O(6), was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intramolecular edge-to-face C—H⋯π contact with an interplanar angle of 56.4° and a H⋯centroid distance of 3.03 Å. |
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