(2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate

The title compound, C(27)H(30)O(6), was prepared by monodihydroxy­lation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenyl­pent-4-enoate using standard Sharpless asymmetric dihydroxy­lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the...

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Detalles Bibliográficos
Autores principales: Fox, David J., Pedersen, Daniel Sejer, Warren, Stuart
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960464/
https://www.ncbi.nlm.nih.gov/pubmed/21201549
http://dx.doi.org/10.1107/S1600536808002651
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author Fox, David J.
Pedersen, Daniel Sejer
Warren, Stuart
author_facet Fox, David J.
Pedersen, Daniel Sejer
Warren, Stuart
author_sort Fox, David J.
collection PubMed
description The title compound, C(27)H(30)O(6), was prepared by monodihydroxy­lation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenyl­pent-4-enoate using standard Sharpless asymmetric dihydroxy­lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intra­molecular edge-to-face C—H⋯π contact with an inter­planar angle of 56.4° and a H⋯centroid distance of 3.03 Å.
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spelling pubmed-29604642010-12-30 (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate Fox, David J. Pedersen, Daniel Sejer Warren, Stuart Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(27)H(30)O(6), was prepared by monodihydroxy­lation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenyl­pent-4-enoate using standard Sharpless asymmetric dihydroxy­lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intra­molecular edge-to-face C—H⋯π contact with an inter­planar angle of 56.4° and a H⋯centroid distance of 3.03 Å. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960464/ /pubmed/21201549 http://dx.doi.org/10.1107/S1600536808002651 Text en © Fox et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fox, David J.
Pedersen, Daniel Sejer
Warren, Stuart
(2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate
title (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate
title_full (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate
title_fullStr (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate
title_full_unstemmed (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate
title_short (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate
title_sort (2s,4′r,5′r)-(e)-tert-butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth­yl)-5-phenyl­pent-4-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960464/
https://www.ncbi.nlm.nih.gov/pubmed/21201549
http://dx.doi.org/10.1107/S1600536808002651
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AT warrenstuart 2s4r5retertbutyl2acetyl22oxo5phenyl13dioxolan4ylmethyl5phenylpent4enoate

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