Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)

The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra­hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol­ecules are inter­connected into chains along the c axis by weak C—H⋯S inter­...

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Detalles Bibliográficos
Autores principales: Tarafder, M. T. H., Islam, M. Toihidul, Islam, M. A. A. A. A., Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960465/
https://www.ncbi.nlm.nih.gov/pubmed/21201362
http://dx.doi.org/10.1107/S1600536808002262
Descripción
Sumario:The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra­hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol­ecules are inter­connected into chains along the c axis by weak C—H⋯S inter­molecular inter­actions. The crystal packing is further stabilized by C—H⋯π inter­actions.

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