Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)

The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra­hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol­ecules are inter­connected into chains along the c axis by weak C—H⋯S inter­...

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Detalles Bibliográficos
Autores principales: Tarafder, M. T. H., Islam, M. Toihidul, Islam, M. A. A. A. A., Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960465/
https://www.ncbi.nlm.nih.gov/pubmed/21201362
http://dx.doi.org/10.1107/S1600536808002262
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author Tarafder, M. T. H.
Islam, M. Toihidul
Islam, M. A. A. A. A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Tarafder, M. T. H.
Islam, M. Toihidul
Islam, M. A. A. A. A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Tarafder, M. T. H.
collection PubMed
description The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra­hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol­ecules are inter­connected into chains along the c axis by weak C—H⋯S inter­molecular inter­actions. The crystal packing is further stabilized by C—H⋯π inter­actions.
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spelling pubmed-29604652010-12-30 Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II) Tarafder, M. T. H. Islam, M. Toihidul Islam, M. A. A. A. A. Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra­hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol­ecules are inter­connected into chains along the c axis by weak C—H⋯S inter­molecular inter­actions. The crystal packing is further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2008-01-25 /pmc/articles/PMC2960465/ /pubmed/21201362 http://dx.doi.org/10.1107/S1600536808002262 Text en © Tarafder et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tarafder, M. T. H.
Islam, M. Toihidul
Islam, M. A. A. A. A.
Chantrapromma, Suchada
Fun, Hoong-Kun
Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)
title Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)
title_full Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)
title_fullStr Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)
title_full_unstemmed Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)
title_short Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]copper(II)
title_sort bis[benzyl n′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) n′,s]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960465/
https://www.ncbi.nlm.nih.gov/pubmed/21201362
http://dx.doi.org/10.1107/S1600536808002262
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