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trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II)

In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxyl­ate O atoms of the isonicotinate ions in axial positions, resulting in a tetra­gonally distorted...

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Detalles Bibliográficos
Autores principales: Han, Jeong Hyeong, Kim, Bong Gon, Min, Kil Sik
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960468/
https://www.ncbi.nlm.nih.gov/pubmed/21201324
http://dx.doi.org/10.1107/S1600536808001116
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author Han, Jeong Hyeong
Kim, Bong Gon
Min, Kil Sik
author_facet Han, Jeong Hyeong
Kim, Bong Gon
Min, Kil Sik
author_sort Han, Jeong Hyeong
collection PubMed
description In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxyl­ate O atoms of the isonicotinate ions in axial positions, resulting in a tetra­gonally distorted octa­hedron. An offset face-to-face π–π stacking inter­action [centroid–centroid distance = 3.674(4) Å] and N—H⋯N and N—H⋯O hydrogen-bonding inter­actions give rise to a one-dimensional supra­molecular structure in the solid state.
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spelling pubmed-29604682010-12-30 trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II) Han, Jeong Hyeong Kim, Bong Gon Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxyl­ate O atoms of the isonicotinate ions in axial positions, resulting in a tetra­gonally distorted octa­hedron. An offset face-to-face π–π stacking inter­action [centroid–centroid distance = 3.674(4) Å] and N—H⋯N and N—H⋯O hydrogen-bonding inter­actions give rise to a one-dimensional supra­molecular structure in the solid state. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960468/ /pubmed/21201324 http://dx.doi.org/10.1107/S1600536808001116 Text en © Han et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Jeong Hyeong
Kim, Bong Gon
Min, Kil Sik
trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II)
title trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II)
title_full trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II)
title_fullStr trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II)
title_full_unstemmed trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II)
title_short trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(II)
title_sort trans-(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)diisonicotinatonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960468/
https://www.ncbi.nlm.nih.gov/pubmed/21201324
http://dx.doi.org/10.1107/S1600536808001116
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