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trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)
In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxylate O atoms of the isonicotinate ions in axial positions, resulting in a tetragonally distorted...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960468/ https://www.ncbi.nlm.nih.gov/pubmed/21201324 http://dx.doi.org/10.1107/S1600536808001116 |
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author | Han, Jeong Hyeong Kim, Bong Gon Min, Kil Sik |
author_facet | Han, Jeong Hyeong Kim, Bong Gon Min, Kil Sik |
author_sort | Han, Jeong Hyeong |
collection | PubMed |
description | In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxylate O atoms of the isonicotinate ions in axial positions, resulting in a tetragonally distorted octahedron. An offset face-to-face π–π stacking interaction [centroid–centroid distance = 3.674(4) Å] and N—H⋯N and N—H⋯O hydrogen-bonding interactions give rise to a one-dimensional supramolecular structure in the solid state. |
format | Text |
id | pubmed-2960468 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604682010-12-30 trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II) Han, Jeong Hyeong Kim, Bong Gon Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxylate O atoms of the isonicotinate ions in axial positions, resulting in a tetragonally distorted octahedron. An offset face-to-face π–π stacking interaction [centroid–centroid distance = 3.674(4) Å] and N—H⋯N and N—H⋯O hydrogen-bonding interactions give rise to a one-dimensional supramolecular structure in the solid state. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960468/ /pubmed/21201324 http://dx.doi.org/10.1107/S1600536808001116 Text en © Han et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Han, Jeong Hyeong Kim, Bong Gon Min, Kil Sik trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II) |
title |
trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II) |
title_full |
trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II) |
title_fullStr |
trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II) |
title_full_unstemmed |
trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II) |
title_short |
trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II) |
title_sort | trans-(1,8-dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960468/ https://www.ncbi.nlm.nih.gov/pubmed/21201324 http://dx.doi.org/10.1107/S1600536808001116 |
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