Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV)

The title compound, [Hf(3)(C(6)H(7))(6)Cl(2)O(2)], is a trinuclear mol­ecule having two (MeCp)(2)HfCl units (MeCp is methyl­cyclo­penta­dien­yl) each connected to an (MeCp)(2)Hf unit by an oxide bridge. The two Hf—O—Hf bridges are nearly linear. The geometry of the three Hf atoms is tetra­hedral (as...

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Detalles Bibliográficos
Autores principales: Wisniewska, Aleksandra, Baranowska, Katarzyna, Pikies, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960469/
https://www.ncbi.nlm.nih.gov/pubmed/21201320
http://dx.doi.org/10.1107/S1600536807061417
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author Wisniewska, Aleksandra
Baranowska, Katarzyna
Pikies, Jerzy
author_facet Wisniewska, Aleksandra
Baranowska, Katarzyna
Pikies, Jerzy
author_sort Wisniewska, Aleksandra
collection PubMed
description The title compound, [Hf(3)(C(6)H(7))(6)Cl(2)O(2)], is a trinuclear mol­ecule having two (MeCp)(2)HfCl units (MeCp is methyl­cyclo­penta­dien­yl) each connected to an (MeCp)(2)Hf unit by an oxide bridge. The two Hf—O—Hf bridges are nearly linear. The geometry of the three Hf atoms is tetra­hedral (assuming the MeCp group occupies one coordination site); the O—Hf—O angle is 99.8 (5)°. One of the Cl atoms is disordered, with site occupancies of 0.61 (7) and 0.39 (7).
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spelling pubmed-29604692010-12-30 Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV) Wisniewska, Aleksandra Baranowska, Katarzyna Pikies, Jerzy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Hf(3)(C(6)H(7))(6)Cl(2)O(2)], is a trinuclear mol­ecule having two (MeCp)(2)HfCl units (MeCp is methyl­cyclo­penta­dien­yl) each connected to an (MeCp)(2)Hf unit by an oxide bridge. The two Hf—O—Hf bridges are nearly linear. The geometry of the three Hf atoms is tetra­hedral (assuming the MeCp group occupies one coordination site); the O—Hf—O angle is 99.8 (5)°. One of the Cl atoms is disordered, with site occupancies of 0.61 (7) and 0.39 (7). International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960469/ /pubmed/21201320 http://dx.doi.org/10.1107/S1600536807061417 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wisniewska, Aleksandra
Baranowska, Katarzyna
Pikies, Jerzy
Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV)
title Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV)
title_full Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV)
title_fullStr Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV)
title_full_unstemmed Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV)
title_short Dichlorido-1κCl,3κCl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trihafnium(IV)
title_sort dichlorido-1κcl,3κcl-hexa­kis[1,1,2,2,3,3(η(5))-methyl­cyclo­penta­dienyl]di-μ(2)-oxido-1:2κ(2) o:o;2:3κ(2) o:o-trihafnium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960469/
https://www.ncbi.nlm.nih.gov/pubmed/21201320
http://dx.doi.org/10.1107/S1600536807061417
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AT baranowskakatarzyna dichlorido1kcl3kclhexakis112233ē5methylcyclopentadienyldim2oxido12k2oo23k2ootrihafniumiv
AT pikiesjerzy dichlorido1kcl3kclhexakis112233ē5methylcyclopentadienyldim2oxido12k2oo23k2ootrihafniumiv

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