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Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV)
The asymmetric unit of the title compound, (C(7)H(10)N)(2)[PtCl(6)], contains one independent protonated 2,6-dimethylpyridinium cation and half of a centrosymmetric [PtCl(6)](2−) anion. The Pt atom has an octahedral coordination. In the crystal structure, intermolecular N—H⋯Cl and C—H⋯Cl hydrogen...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960473/ https://www.ncbi.nlm.nih.gov/pubmed/21201599 http://dx.doi.org/10.1107/S1600536808025257 |
| _version_ | 1782188748038995968 |
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| author | Amani, Vahid Rahimi, Rahmatollah Khavasi, Hamid Reza |
| author_facet | Amani, Vahid Rahimi, Rahmatollah Khavasi, Hamid Reza |
| author_sort | Amani, Vahid |
| collection | PubMed |
| description | The asymmetric unit of the title compound, (C(7)H(10)N)(2)[PtCl(6)], contains one independent protonated 2,6-dimethylpyridinium cation and half of a centrosymmetric [PtCl(6)](2−) anion. The Pt atom has an octahedral coordination. In the crystal structure, intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds result in the formation of a supramolecular structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 4.235 (1) Å]. |
| format | Text |
| id | pubmed-2960473 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29604732010-12-30 Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV) Amani, Vahid Rahimi, Rahmatollah Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(7)H(10)N)(2)[PtCl(6)], contains one independent protonated 2,6-dimethylpyridinium cation and half of a centrosymmetric [PtCl(6)](2−) anion. The Pt atom has an octahedral coordination. In the crystal structure, intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds result in the formation of a supramolecular structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 4.235 (1) Å]. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960473/ /pubmed/21201599 http://dx.doi.org/10.1107/S1600536808025257 Text en © Amani et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Amani, Vahid Rahimi, Rahmatollah Khavasi, Hamid Reza Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV) |
| title | Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV) |
| title_full | Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV) |
| title_fullStr | Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV) |
| title_full_unstemmed | Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV) |
| title_short | Bis(2,6-dimethylpyridinium) hexachloridoplatinate(IV) |
| title_sort | bis(2,6-dimethylpyridinium) hexachloridoplatinate(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960473/ https://www.ncbi.nlm.nih.gov/pubmed/21201599 http://dx.doi.org/10.1107/S1600536808025257 |
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