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Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4) O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate
In the title binuclear iron(III) complex, [Fe(2)(C(14)H(10)N(2)O(2))(3)]·4C(4)H(8)O or [Fe(2)(salda)(3)]·4THF [H(2)salda = 2,2′-(azinidimethylene)diphenolate and THF is tetrahydrofuran], the ligand possesses a rotationally flexible single N—N bond. Three dinucleating O,N:N′,O′-donor ligands provi...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960474/ https://www.ncbi.nlm.nih.gov/pubmed/21201645 http://dx.doi.org/10.1107/S1600536808027438 |
| _version_ | 1782188748305334272 |
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| author | Wang, Jinglin Liu, Bin Yang, Binsheng |
| author_facet | Wang, Jinglin Liu, Bin Yang, Binsheng |
| author_sort | Wang, Jinglin |
| collection | PubMed |
| description | In the title binuclear iron(III) complex, [Fe(2)(C(14)H(10)N(2)O(2))(3)]·4C(4)H(8)O or [Fe(2)(salda)(3)]·4THF [H(2)salda = 2,2′-(azinidimethylene)diphenolate and THF is tetrahydrofuran], the ligand possesses a rotationally flexible single N—N bond. Three dinucleating O,N:N′,O′-donor ligands provide three diazine (=N—N=) bridges between the metal ions, yielding a binuclear triple helicate structure with crystallographic C (2) symmetry, the rotation axis bisecting one N—N bond. |
| format | Text |
| id | pubmed-2960474 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29604742010-12-30 Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4) O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate Wang, Jinglin Liu, Bin Yang, Binsheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear iron(III) complex, [Fe(2)(C(14)H(10)N(2)O(2))(3)]·4C(4)H(8)O or [Fe(2)(salda)(3)]·4THF [H(2)salda = 2,2′-(azinidimethylene)diphenolate and THF is tetrahydrofuran], the ligand possesses a rotationally flexible single N—N bond. Three dinucleating O,N:N′,O′-donor ligands provide three diazine (=N—N=) bridges between the metal ions, yielding a binuclear triple helicate structure with crystallographic C (2) symmetry, the rotation axis bisecting one N—N bond. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960474/ /pubmed/21201645 http://dx.doi.org/10.1107/S1600536808027438 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Jinglin Liu, Bin Yang, Binsheng Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4) O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4)
O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_full | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4)
O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_fullStr | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4)
O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_full_unstemmed | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4)
O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_short | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4)
O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_sort | tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ(4)
o,n:n′,o′]diiron(iii) tetrahydrofuran tetrasolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960474/ https://www.ncbi.nlm.nih.gov/pubmed/21201645 http://dx.doi.org/10.1107/S1600536808027438 |
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