Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate

In the title compound, [AuCl(2)(C(9)H(12)N)(2)][AuCl(4)]·C(2)H(3)N, there is a mirror plane passing through Au and the central C—C bond of the bipyridyl ligand in the cation, and through Au and two Cl atoms of the anion. A cis-AuCl(2)N(2) square-planar geometry for the cation and a square-planar AuC...

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Autores principales: Yıldırım, Sema Öztürk, Akkurt, Mehmet, Safari, Nasser, Amani, Vahid, McKee, Vickie, Abedi, Anita, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960475/
https://www.ncbi.nlm.nih.gov/pubmed/21201629
http://dx.doi.org/10.1107/S1600536808025646
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author Yıldırım, Sema Öztürk
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
McKee, Vickie
Abedi, Anita
Khavasi, Hamid Reza
author_facet Yıldırım, Sema Öztürk
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
McKee, Vickie
Abedi, Anita
Khavasi, Hamid Reza
author_sort Yıldırım, Sema Öztürk
collection PubMed
description In the title compound, [AuCl(2)(C(9)H(12)N)(2)][AuCl(4)]·C(2)H(3)N, there is a mirror plane passing through Au and the central C—C bond of the bipyridyl ligand in the cation, and through Au and two Cl atoms of the anion. A cis-AuCl(2)N(2) square-planar geometry for the cation and a square-planar AuCl(4) geometry for the anion result. The two C atoms and the N atom of the acetonitrile mol­ecule all have m site symmetries. In the crystal structure, weak C—H⋯Cl inter­actions may help to establish the packing.
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spelling pubmed-29604752010-12-30 Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate Yıldırım, Sema Öztürk Akkurt, Mehmet Safari, Nasser Amani, Vahid McKee, Vickie Abedi, Anita Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [AuCl(2)(C(9)H(12)N)(2)][AuCl(4)]·C(2)H(3)N, there is a mirror plane passing through Au and the central C—C bond of the bipyridyl ligand in the cation, and through Au and two Cl atoms of the anion. A cis-AuCl(2)N(2) square-planar geometry for the cation and a square-planar AuCl(4) geometry for the anion result. The two C atoms and the N atom of the acetonitrile mol­ecule all have m site symmetries. In the crystal structure, weak C—H⋯Cl inter­actions may help to establish the packing. International Union of Crystallography 2008-08-20 /pmc/articles/PMC2960475/ /pubmed/21201629 http://dx.doi.org/10.1107/S1600536808025646 Text en © Yıldırım et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yıldırım, Sema Öztürk
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
McKee, Vickie
Abedi, Anita
Khavasi, Hamid Reza
Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate
title Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate
title_full Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate
title_fullStr Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate
title_full_unstemmed Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate
title_short Dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III) tetrachlorido­aurate(III) acetonitrile solvate
title_sort dichlorido(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) n,n′)gold(iii) tetrachlorido­aurate(iii) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960475/
https://www.ncbi.nlm.nih.gov/pubmed/21201629
http://dx.doi.org/10.1107/S1600536808025646
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AT akkurtmehmet dichlorido44ditertbutyl22bipyridinek2nngoldiiitetrachloridoaurateiiiacetonitrilesolvate
AT safarinasser dichlorido44ditertbutyl22bipyridinek2nngoldiiitetrachloridoaurateiiiacetonitrilesolvate
AT amanivahid dichlorido44ditertbutyl22bipyridinek2nngoldiiitetrachloridoaurateiiiacetonitrilesolvate
AT mckeevickie dichlorido44ditertbutyl22bipyridinek2nngoldiiitetrachloridoaurateiiiacetonitrilesolvate
AT abedianita dichlorido44ditertbutyl22bipyridinek2nngoldiiitetrachloridoaurateiiiacetonitrilesolvate
AT khavasihamidreza dichlorido44ditertbutyl22bipyridinek2nngoldiiitetrachloridoaurateiiiacetonitrilesolvate

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