Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)

The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra­hedra, forming an octa­nuclear V/S/Cu cluster with C (i) symmetry. The geometry around the V atoms is slightly distorted tetra­hedral, while there are large distortions from ideal...

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Detalles Bibliográficos
Autores principales: Yu, Zhang, Tang, Guodong, Zhao, Jianying, Jiang, Zhengjing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960477/
https://www.ncbi.nlm.nih.gov/pubmed/21201649
http://dx.doi.org/10.1107/S1600536808027165
Descripción
Sumario:The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra­hedra, forming an octa­nuclear V/S/Cu cluster with C (i) symmetry. The geometry around the V atoms is slightly distorted tetra­hedral, while there are large distortions from ideal tetra­hedral geometry for the Cu atoms. Adjacent metal–metal distances range from 2.693 (1) to 2.772 (10) Å, indicating weak metal–metal inter­actions in the cluster.

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